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1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra-hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone.

ABSTRACT: In the title compound, C(14)H(14)BrNO(2)S, there are two similar non-equivalent mol-ecules in the asymmetric unit, displaying three chiral centres each. In the crystal structure, they are linked by inter-molecular N-H?O hydrogen bonds to form infinite chains, which are in turn connected by weak Br?H and S?H inter-actions.

SUBMITTER: Palamarchuk GV

PROVIDER: S-EPMC2968576 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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1-(8-Bromo-2-methyl-4-thioxo-3,4,5,6-tetra-hydro-2H-2,6-methano-1,3-benzoxazocin-11-yl)ethanone.

Palamarchuk G V GV Borisov O V OV Kovalenko S S SS Chernykh V P VP Kovalenko S M SM Baumer V N VN Shishkin O V OV

Acta crystallographica. Section E, Structure reports online 20090204 Pt 3

In the title compound, C(14)H(14)BrNO(2)S, there are two similar non-equivalent mol-ecules in the asymmetric unit, displaying three chiral centres each. In the crystal structure, they are linked by inter-molecular N-H⋯O hydrogen bonds to form infinite chains, which are in turn connected by weak Br⋯H and S⋯H inter-actions. ...[more]

PMID: 21582133

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Crystal structure of ethyl (2S)-9-meth-oxy-2-methyl-4-oxo-3,4,5,6-tetra-hydro-2H- 2,6-methano-benzo[g][1,3,5]oxa-diazocine-11-carboxyl-ate.

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