Unknown

Dataset Information

0

Poly[[[diisothio-cyanato-cobalt(II)]-bis-[?-4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol]] dimethyl-formamide disolvate dihydrate].

ABSTRACT: In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol (L) ligands, and by two N atoms from two axial thio-cyanate anions [Co-N = 2.104?(3)-2.144?(3)?Å]. The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane. The dimethyl-formamide and solvent water mol-ecules participate in inter-molecular O-H?O and O-H?S hydrogen bonds, which consolidate the crystal packing.

SUBMITTER: Chu ZL 

PROVIDER: S-EPMC2968591 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Poly[[[diisothio-cyanato-cobalt(II)]-bis-[μ-4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol]] dimethyl-formamide disolvate dihydrate].

Chu Zhao-Lian ZL  

Acta crystallographica. Section E, Structure reports online 20090218 Pt 3

In the title compound, {[Co(NCS)(2)(C(16)H(20)N(6)O)(2)]·2C(3)H(7)NO·2H(2)O}(n), each Co(II) ion located on an inversion center is six-coordinated by four equatorial N atoms from four different 4-tert-butyl-2,6-bis-(1,2,4-triazol-1-ylmeth-yl)phenol (L) ligands, and by two N atoms from two axial thio-cyanate anions [Co-N = 2.104 (3)-2.144 (3) Å]. The metal centres are connected via the bidentate L ligands into two-dimensional polymeric layers parallel to bc plane. The dimethyl-formamide and solve  ...[more]

Similar Datasets

Unknown 4,4'-Bis(1,2,4-triazol-1-ylmeth-yl)biphen-yl.
| S-EPMC2970468 | biostudies-literature
Unknown 1,4-Bis(4H-1,2,4-triazol-4-yl)benzene dihydrate.
| S-EPMC3414318 | biostudies-literature
Unknown 2,6-Bis(4H-1,2,4-triazol-4-yl)pyridine dihydrate.
| S-EPMC3247355 | biostudies-literature
Unknown 2,6-Bis(4H-1,2,4-triazol-4-yl)pyridine dihydrate.
| S-EPMC3151751 | biostudies-literature
Unknown Bis(?-3,5-dimethyl-4H-1,2,4-triazol-4-amine-?N:N)bis-[bis-(thio-cyanato-?N)zinc]-bis-(3,5-dimethyl-4H-1,2,4-triazol-4-amine-?N)bis-(thio-cyanato-?N)zinc (1/2).
| S-EPMC3212172 | biostudies-literature
Unknown Bis[bis-(1-ethyl-benzimidazol-2-ylmeth-yl) ether]cobalt(II) dipicrate dimethyl-formamide disolvate.
| S-EPMC2970309 | biostudies-literature
Unknown Diaqua-bis-[2,6-bis-(4H-1,2,4-triazol-4-yl)pyridine-?N(2)]bis-(seleno-cyanato-?N)cobalt(II).
| S-EPMC3414148 | biostudies-literature
Unknown Bis(5-amino-3-carb-oxy-1H-1,2,4-triazol-4-ium) sulfate dihydrate.
| S-EPMC3089095 | biostudies-literature
Unknown catena-Poly[[diaqua-dichlorido-manganese(II)]-?-1,1'-bis-(1H-1,2,4-triazol-1-ylmeth-yl)ferrocene].
| S-EPMC2980034 | biostudies-literature
Unknown 2-(4H-1,2,4-Triazol-4-yl)phenol.
| S-EPMC3007949 | biostudies-literature