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Propyl 2-(5-chloro-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.

ABSTRACT: In the title compound, C(14)H(15)ClO(4)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The crystal structure is stabilized by aromatic ?-? inter-actions between the benzene rings of neighbouring mol-ecules [centroid-to-centroid distance = 3.635?(3)?Å], and by C-H?? inter-actions between a propyl methyl-ene H atom and the furan ring of an adjacent mol-ecule. In addition, the crystal structure exhibits weak inter-molecular C-H?O hydrogen bonds.

SUBMITTER: Choi HD

PROVIDER: S-EPMC2968603 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Propyl 2-(5-chloro-3-methyl-sulfinyl-1-benzofuran-2-yl)acetate.

Choi Hong Dae HD Seo Pil Ja PJ Son Byeng Wha BW Lee Uk U

Acta crystallographica. Section E, Structure reports online 20090213 Pt 3

In the title compound, C(14)H(15)ClO(4)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The crystal structure is stabilized by aromatic π-π inter-actions between the benzene rings of neighbouring mol-ecules [centroid-to-centroid distance = 3.635 (3) Å], and by C-H⋯π inter-actions between a propyl methyl-ene H atom and the furan ring of an adjacent mol-ecule. In addition, the crystal structure exhibits weak inter- ...[more]

PMID: 21582184

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