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Chlorido{2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-?O,N,N',O'}manganese(III).

ABSTRACT: In the title complex, [Mn(C(17)H(16)N(2)O(2))Cl], the Mn(III) ion is coordinated by two O [Mn-O = 1.719?(2) and 1.813?(2)?Å] and two N [Mn-N = 1.824?(2) and 1.931?(2)?Å] atoms from the tetra-dentate Schiff base ligand and a chloride anion [Mn-Cl = 2.9634?(16)?Å] in a square-pyramidal geometry. In the ligand, the two benzene rings form a dihedral angle of 68.06?(5)°.

SUBMITTER: Li MJ

PROVIDER: S-EPMC2968646 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Chlorido{2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).

Li Ming-Jie MJ Yan Peng-Fei PF Li Guang-Ming GM Li Hong-Feng HF

Acta crystallographica. Section E, Structure reports online 20090221 Pt 3

In the title complex, [Mn(C(17)H(16)N(2)O(2))Cl], the Mn(III) ion is coordinated by two O [Mn-O = 1.719 (2) and 1.813 (2) Å] and two N [Mn-N = 1.824 (2) and 1.931 (2) Å] atoms from the tetra-dentate Schiff base ligand and a chloride anion [Mn-Cl = 2.9634 (16) Å] in a square-pyramidal geometry. In the ligand, the two benzene rings form a dihedral angle of 68.06 (5)°. ...[more]

PMID: 21582084

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