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2-Ferrocenyl-N-(2-ferrocenylbenzo-yl)-N-(4-methyl-2-pyrid-yl)benzamide.

ABSTRACT: The title compound, [Fe(2)(C(5)H(5))(2)(C(30)H(22)N(2)O(2))], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methyl-pyridine, forms a twisted mol-ecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intra-molecular C-H?? interaction is observed involving a substituted ?(5)-C(5)H(4) ring and an ortho H atom of the benzene ring on the opposite side of the mol-ecule. In the crystal structure, there are no classical hydrogen bonds: inter-actions comprise a short C(6)-H??(C(6)) inter-action involving substituted benzene rings and two C-H?O=C inter-actions per mol-ecule.

SUBMITTER: Gallagher JF

PROVIDER: S-EPMC2968647 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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2-Ferrocenyl-N-(2-ferrocenylbenzo-yl)-N-(4-methyl-2-pyrid-yl)benzamide.

Gallagher John F JF Alley Steven S Lough Alan J AJ

Acta crystallographica. Section E, Structure reports online 20090228 Pt 3

The title compound, [Fe(2)(C(5)H(5))(2)(C(30)H(22)N(2)O(2))], a 2:1 product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-4-methyl-pyridine, forms a twisted mol-ecular structure in the solid state due to steric effects from the two benzene rings ortho-substituted with ferrocenyl and carbonyl-derived groups. A short intra-molecular C-H⋯π interaction is observed involving a substituted η(5)-C(5)H(4) ring and an ortho H atom of the benzene ring on the opposite side of the mol-ecule. In th ...[more]

PMID: 21582102

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