Bis(1,3-benzothia-zol-2-amine-?N)silver(I) nitrate acetone solvate.

ABSTRACT: In the title compound, [Ag(C(7)H(6)N(2)S)(2)]NO(3)·C(3)H(6)O, the Ag(I) ion is coordinated to two benzothia-zol-2-amine ligands via the thia-zole N atoms in an approximately linear arrangement. The dihedral angle between the mean planes of the two 1,3-benzothia-zole groups is 5.9?(3)°. Both amine groups on the ligands are oriented in the same direction and are engaged in N-H?O hydrogen bonding with the nitrate counter-anion, forming one-dimensional columns along the b-axis direction. Voids created by inefficient crystal packing are occupied by acetone solvent mol-ecules which are disordered over two sites with occupancies of 0.563?(11) and 0.437?(11).

SUBMITTER: Strasser CE 

PROVIDER: S-EPMC2968676 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature