Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

4-[2-(4-Fluoro-phen-yl)furan-3-yl]pyridine.

ABSTRACT: In the crystal structure of the title compound, C(15)H(10)FNO, the furan ring makes dihedral angles of 40.04?(11) and 25.71?(11)° with the pyridine and 4-fluoro-phenyl rings, respectively. The pyridine ring makes a dihedral angle of 49.51?(10)° with the 4-fluoro-phenyl ring. Non-conventional C-H?F and C-H?N hydrogen bonds are effective in the stabilization of the crystal structure.

SUBMITTER: Abu Thaher B

PROVIDER: S-EPMC2968695 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

4-[2-(4-Fluoro-phen-yl)furan-3-yl]pyridine.

Abu Thaher Bassam B Koch Pierre P Schollmeyer Dieter D Laufer Stefan S

Acta crystallographica. Section E, Structure reports online 20090204 Pt 3

In the crystal structure of the title compound, C(15)H(10)FNO, the furan ring makes dihedral angles of 40.04 (11) and 25.71 (11)° with the pyridine and 4-fluoro-phenyl rings, respectively. The pyridine ring makes a dihedral angle of 49.51 (10)° with the 4-fluoro-phenyl ring. Non-conventional C-H⋯F and C-H⋯N hydrogen bonds are effective in the stabilization of the crystal structure. ...[more]

PMID: 21582130

Similar Datasets

2-Fluoro-5-(4-fluoro-phen-yl)pyridine.

Project description:In the title compound, C(11)H(7)F(2)N, the fluoro-benzene and the 2-fluoro-pyridine rings are oriented at a dihedral angle of 37.93?(5)°. In the crystal, only van der Waals inter-actions occur.

| S-EPMC3393334 | biostudies-literature

5-(2,3-Dichloro-phen-yl)-2-fluoro-pyridine.

Project description:In the title compound, C(11)H(6)Cl(2)FN, the dichloro-benzene and the 2-fluoro-pyridine rings are oriented at a dihedral angle of 47.73 (3)°. In the crystal, pairs of C-H⋯N inter-actions link the mol-ecules into dimers with R(2) (2)(12) motifs. Mol-ecules are arranged in stacks extending along [100] via π-π inter-actions with a centroid-centroid distance of 3.8889 (3) Å.

| S-EPMC3393983 | biostudies-literature

5-Fluoro-2-(2-fluoro-phen-yl)-3-methyl-sulfinyl-1-benzo-furan.

Project description:In the title compound, C15H10F2O2S, the dihedral angle between the plane of the benzo-furan ring system (r.m.s. deviation = 0.015?Å) and that of the 2-fluoro-phenyl ring is 28.53?(6)°. In the crystal, mol-ecules are linked by C-H?O and C-H?F hydrogen bonds, and by ?-? inter-actions between the furan and benzene rings of neighbouring mol-ecules [centroid-centroid distance = 3.625?(2)?Å], forming a three-dimensional network.

| S-EPMC4120583 | biostudies-literature

4-[2-(4-Fluoro-phen-yl)-1H-pyrrol-3-yl]pyridine.

Project description:In the crystal structure of the title compound, C(15)H(11)FN(2), the pyrrole ring makes dihedral angles of 33.19?(9) and 36.33?(10)° with the pyridine and 4-fluoro-phenyl rings, respectively. The pyridine ring makes a dihedral angle of 46.59?(9)° with the 4-fluoro-phenyl ring. In the crystal structure, an N-H?N hydrogen bond joins the mol-ecules into chains.

| S-EPMC2968667 | biostudies-literature

5-(4-Fluoro-phen-yl)-2-(4-methyl-phen-yl)-3-methyl-sulfanyl-1-benzo-furan.

Project description:The asymmetric unit of the title compound, C22H17FOS, contains two independent mol-ecules (A and B). The dihedral angles between the benzo-furan ring systems [r.m.s. deviations of 0.026 (1), 0.004 (1) and 0.003 (1) Å, respectively, for mol-ecule A, and 0.002 (1), 0.004 (1) and 0.005 (1) Å for B] and the pendant 4-fluoro-phenyl and 4-methyl-phenyl rings are 39.48 (4) and 30.86 (5)°, respectively, for mol-ecule A, and 33.34 (6) and 20.99 (8)° for B. In the crystal, mol-ecules are linked by weak C-H⋯F and C-H⋯π inter-actions, resulting in a three-dimensional network.

| S-EPMC3998457 | biostudies-literature

2-(4-Fluoro-phen-yl)-1-(phenyl-sulfin-yl)-naphtho-[2,1-b]furan.

Project description:In the title compound, C(24)H(15)FO(2)S, the 4-fluoro-phenyl ring makes a dihedral angle of 19.43?(4)° with the mean plane of the naphtho-furan fragment. The dihedral angle between the phenyl ring and the mean plane of the naphtho-furan fragment is 85.83?(4)°. In the crystal, mol-ecules are linked by weak inter-molecular C-H?O hydrogen bonds.

| S-EPMC3200676 | biostudies-literature

5-Fluoro-2-(4-fluoro-phen-yl)-7-methyl-3-phenyl-sulfinyl-1-benzo-furan.

Project description:In the title compound, C21H14F2O2S, the dihedral angles between the mean plane [r.m.s. deviation = 0.007?(2)?Å] of the benzo-furan ring system and the pendant 4-fluoro-phenyl and phenyl rings are 5.93?(9) and 80.23?(5)°, respectively. In the crystal, mol-ecules are linked by weak C-H?O and C-H?? inter-actions, forming a three-dimensional network.

| S-EPMC3770441 | biostudies-literature

2-Vinyl-pyridine-tris-(penta-fluoro-phen-yl)borane hexane monosolvate.

Project description:The title compound, C(7)H(7)N·B(C(6)F(5))(3)·C(6)H(14), was obtained by the stoichiometric reaction of 2-vinyl-pyridine and tris-(penta-fluoro-phen-yl)borane in toluene. The formed adduct exhibits a restricted rotation along the B-N bond resulting in an asymmetry, which can be also observed in the (19)F NMR spectra. The B-N distance is equivalent to the distances found for 2-methyl-pyridine and 2-ethyl-pyridine B(C(6)F(5))(3) adducts. For the final refinement, the contributions of disordered solvent mol-ecules were removed from the diffraction data with SQUEEZE in PLATON [van der Sluis & Spek (1990). Acta Cryst. A46, 194-201; Spek (2009). Acta Cryst. D65, 148-155].

| S-EPMC3344187 | biostudies-literature

5-(5-Bromo-2-meth-oxy-phen-yl)-2-fluoro-pyridine.

Project description:In the title compound, C(12)H(9)BrFNO, the dihedral angle between the aromatic rings is 51.39?(5)°; the C atom of the meth-oxy group is close to being coplanar with its attached ring (r.m.s. deviation = 0.0172?Å] and is oriented away from the pyridine ring. In the crystal, mol-ecules inter-act by van der Waals forces.

| S-EPMC3435681 | biostudies-literature

Dibromido{2-[(4-fluoro-phen-yl)imino-meth-yl]pyridine-?(2)N,N'}zinc.

Project description:In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49?(1)°. In the crystal, weak C-H?F and C-H?Br hydrogen bonds are observed.

| S-EPMC3414158 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data