Unknown

Dataset Information

0

2-Bromo-4-chloro-6-[(E)-(2-chloro-phen-yl)imino-meth-yl]phenol.

ABSTRACT: The title compound, C(13)H(8)BrCl(2)NO, was obtained by reaction of 3-bromo-5-chloro-salicylaldehyde and 2-chloro-benzenamine in methanol. The mol-ecule displays an E configuration with respect to the imine C=N double bond. The dihedral angle between the two benzene rings is 4.57 (11)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond. In the crystal structure, mol-ecules are linked by inter-molecular C-H⋯O hydrogen-bonding inter-actions into zigzag chains running parallel to the b axis. Inter-molecular Br⋯Cl [3.5289 (11) Å] and Cl⋯Cl [3.5042 (12) Å] inter-actions are present.

SUBMITTER: Zhang X 

PROVIDER: S-EPMC2968929 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

2-Bromo-4-chloro-6-[(E)-(2-chloro-phen-yl)imino-meth-yl]phenol.

Zhang Xinli X  

Acta crystallographica. Section E, Structure reports online 20090306 Pt 4

The title compound, C(13)H(8)BrCl(2)NO, was obtained by reaction of 3-bromo-5-chloro-salicylaldehyde and 2-chloro-benzenamine in methanol. The mol-ecule displays an E configuration with respect to the imine C=N double bond. The dihedral angle between the two benzene rings is 4.57 (11)°. The mol-ecular conformation is stabilized by an intra-molecular O-H⋯N hydrogen bond. In the crystal structure, mol-ecules are linked by inter-molecular C-H⋯O hydrogen-bonding inter-actions into zigzag chains runn  ...[more]

Similar Datasets

Unknown 4-Bromo-2-[(E)-(4-chloro-phen-yl)imino-meth-yl]phenol.
| S-EPMC3052075 | biostudies-literature
Unknown 2-Bromo-4-chloro-6-[(2,6-diisopropyl-phen-yl)imino-meth-yl]phenol.
| S-EPMC2959941 | biostudies-literature
Unknown 2,4-Di-bromo-6-{[(5-chloro-2-methyl-phen-yl)imino]-meth-yl}phenol.
| S-EPMC3770443 | biostudies-literature
Unknown 2-[(3-Bromo-phen-yl)imino-meth-yl]phenol.
| S-EPMC2960578 | biostudies-literature
Unknown 2-Bromo-4-chloro-6-{(E)-[4-(diethyl-amino)-phen-yl]imino-meth-yl}phenol.
| S-EPMC3008048 | biostudies-literature
Unknown 4-Bromo-2-({4-[(hy-droxy-imino)-meth-yl]phen-yl}imino-meth-yl)phenol.
| S-EPMC3007216 | biostudies-literature
Unknown 4-Chloro-2-[(E)-(2-chloro-phen-yl)imino-meth-yl]phenol.
| S-EPMC2968492 | biostudies-literature
Unknown 2-Chloro-4-{(E)-[(4-chloro-phen-yl)imino]-meth-yl}phenol.
| S-EPMC3295463 | biostudies-literature
Unknown 2-Benzyl-imino-meth-yl-6-bromo-4-chloro-phenol.
| S-EPMC2960476 | biostudies-literature
Unknown 2-[(4-Bromo-phen-yl)imino-meth-yl]-3,5-dimethoxy-phenol.
| S-EPMC2968797 | biostudies-literature