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Bis(2,5-dimethyl-anilinium) tetra-chlorido-zincate(II).

ABSTRACT: In the title compound, (C(8)H(12)N)(2)[ZnCl(4)], the Zn(2+) ion adopts a distorted tetra-hedral coordination geometry. In the crystal, the cations and anions are linked by N-H⋯Cl hydrogen bonds, leading to ribbons propagating parallel to the a axis.

SUBMITTER: Souissi S

PROVIDER: S-EPMC2968953 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Bis(2,3-dimethyl-anilinium) tetra-chlorido-zincate dihydrate.

Project description:In the title compound, (C(8)H(12)N)(2)[ZnCl(4)]·2H(2)O, the Zn atom is coordinated by four Cl atoms in a tetra-hedral geometry. The water mol-ecules and the organic cations inter-act with the [ZnCl(4)](2-) complex anions, building up a two-dimensional hydrogen-bonded network parallel to (100).

| S-EPMC3120428 | biostudies-literature

Bis(tetra-methyl-ammonium) tetra-chlorido-zincate(II), phase VI.

Project description:Phase VI of bis-(tetra-methyl-ammonium) tetra-chloro-zincate(II), (C(4)H(12)N)(2)[ZnCl(4)], contains three formula units per asymmetric unit. Several short C-H⋯Cl contacts [2.70 (3) and 2.72 (4) Å] are observed, but they are believed to participate only in van der Waals inter-actions. The crystal studied exhibited inversion twinning.

| S-EPMC2924214 | biostudies-literature

Bis(2,6-dimethyl-pyridinium) tetra-bromido-zincate(II).

Project description:In the crystal structure of the title compound, (C(7)H(10)N)(2)[ZnBr(4)], the coordination geometry of the anion is approximately tetra-hedral and a twofold rotation axis passes through the Zn atom. The Zn-Br bond lengths range from 2.400 (2) to 2.408 (3) Å and the Br-Zn-Br angles range from 108.14 (6) to 115.15 (15)°. In the crystal structure, the [ZnBr(4)](2-) anion is connected to two cations through N-H⋯Br and H(2)C-H⋯Br hydrogen bonds, forming two-dimensional cation-anion-cation layers normal to the b axis. No significant Br⋯Br inter-actions [the shortest being 4.423 (4) Å] are observed in the structure.

| S-EPMC2977623 | biostudies-literature

Tris(3-methyl-anilinium) tetra-chlorido-zincate chloride hemihydrate.

Project description:The asymmetric unit of the title compound, (C(7)H(10)N)(3)[ZnCl(4)]Cl·0.5H(2)O, consists of three 3-methyl-anilinium cations, one tetrahedral tetra-chloridozincate anion and one chloride anion and a water mol-ecule, which lies on a twofold axis. The components are linked into chains parallel to the a axis by N-H⋯Cl hydrogen bonds.

| S-EPMC3247542 | biostudies-literature

Crystal structure of bis-(4-acetyl-anilinium) tetra-chlorido-mercurate(II).

Project description:The structure of the title salt, (C8H10NO)2[HgCl4], is isotypic with that of the cuprate(II) and cobaltate(II) analogues. The asymmetric unit contains one 4-acetyl-anilinium cation and one half of a tetra-chlorido-mercurate(II) anion (point group symmetry m). The Hg-Cl distances are in the range 2.4308?(7)-2.5244?(11)?Å and the Cl-Hg-Cl angles in the range of 104.66?(2)-122.94?(4)°, indicating a considerable distortion of the tetra-hedral anion. In the crystal, cations are linked by an inter-molecular N-H?O hydrogen-bonding inter-action, leading to a C(8) chain motif with the chains extending parallel to the b axis. There is also a ?-? stacking inter-action with a centroid-to-centroid distance of 3.735?(2)?Å between neighbouring benzene rings along this direction. The anions lie between the chains and inter-act with the cations through inter-molecular N-H?Cl hydrogen bonds, leading to the formation of a three-dimensional network structure.

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2,2'-Diamino-5,5'-dimethyl-4,4'-bi-1,3-thia-zolium tetra-chlorido-zincate(II).

Project description:In the dianion of the title compound, (C(8)H(12)N(4)S(2))[ZnCl(4)], the Zn(II) ion is in a slightly distorted tetra-hedral environment. In the cation, the mean planes of the thia-zole rings form a dihedral angle of 67.81?(6)?Å. In the crystal structure, anions and cations are linked into a three-dimensional network via inter-molecular N-H?Cl hydrogen bonds.

| S-EPMC2971375 | biostudies-literature

Bis(1,10-phenanthrolin-1-ium) tetra-chlorido-zincate monohydrate.

Project description:In the crystal structure of the title compound, (C12H9N2)2[ZnCl4]·H2O, the two independent 1,10-phenanthrolinium cations are bridged by the water mol-ecule and the tetrahedral tetrachloridozincate anion via N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds, forming chains along [100]. The chains are linked via C-H⋯Cl hydrogen bonds and a number of π-π inter-actions [centroid-centroid distances vary from 3.5594 (14) to 3.7057 (13) Å], forming a three-dimensional network. In each 1,10-phenanthrolinium cation, there is a short N-H⋯N inter-action.

| S-EPMC3998259 | biostudies-literature

2,5-Dimethyl-anilinium nitrate.

Project description:In the title salt, C(8)H(12)N(+)·NO(3) (-), all non-H atoms of the cation lie on mirror planes. The nitrate counteranion has m symmetry and acts as a hydrogen-bond acceptor of N-H?O hydrogen bonds, connecting the cations and anions into layers running parallel to the ab plane.

| S-EPMC2977111 | biostudies-literature

2-Methyl-piperazinediium tetra-chlorido-zincate(II).

Project description:The asymmetric unit of the title compound, (C(5)H(14)N(2))[ZnCl(4)], consists of a diprotonated 2-methyl-piperazine cation and a tetra-chloridozincate anion. The Zn(II) ion is in a slightly distorted tetra-hedral coordination environment. The six-membered piperazine ring adopts a chair conformation. The crystal structure is stabilized by inter-molecular N-H?Cl hydrogen bonds.

| S-EPMC2979142 | biostudies-other

Crystal structure of bis-(4-acetyl-anilinium) tetra-chlorido-cobaltate(II).

Project description:The structure of the title salt, (C8H10NO)2[CoCl4], is isotypic with the analogous cuprate(II) structure. The asymmetric unit contains one 4-acetyl-anilinium cation and one half of a tetra-chlorido-cobaltate(II) anion for which the Co(II) atom and two Cl(-) ligands lie on a mirror plane. The Co-Cl distances in the distorted tetra-hedral anion range from 2.2519?(6) to 2.2954?(9)?Å and the Cl-Co-Cl angles range from 106.53?(2) to 110.81?(4)°. In the crystal, cations are self-assembled by inter-molecular N-H?O hydrogen-bonding inter-actions, leading to a C(8) chain motif with the chains running parallel to the b axis. ?-? stacking inter-actions between benzene rings, with a centroid-to-centroid distance of 3.709?Å, are also observed along this direction. The CoCl4 (2-) anions are sandwiched between the cationic chains and inter-act with each other through inter-molecular N-H?Cl hydrogen-bonding inter-actions, forming a three-dimensional network structure.

| S-EPMC4719843 | biostudies-other

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