Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

N'-(3-Bromo-5-chloro-2-hydroxy-benzyl-idene)-3,4,5-trihydroxy-benzohydrazide methanol solvate.

ABSTRACT: The benzohydrazide mol-ecule of the title compound, C(14)H(10)BrClN(2)O(5)·CH(3)OH, is non-planar, the two aromatic rings at either side of the -C(=O)-NH-N=CH- unit being twisted by 5.9 (1)°. The benzohydrazide mol-ecule is linked to the solvent mol-ecule by an O-H⋯O hydrogen bond. Mol-ecules are connected by further O-H⋯O hydrogen bonds and an N-H⋯O link into a two-dimensional array.

SUBMITTER: Abdul Alhadi AA

PROVIDER: S-EPMC2968970 | biostudies-literature |

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Similar Datasets

N'-(5-Bromo-2-hydroxy-benzyl-idene)-3,4,5-trihydroxy-benzohydrazide dihydrate.

Project description:The title compound, C(14)H(11)BrN(2)O(5)·2H(2)O, crystallizes as hydrogen-bonded sheets. The 2-hydr-oxy group on the benzyl-idene group forms an intra-molecular hydrogen bond to the N atom of the C=N double bond. The amino N atom is a hydrogen-bond donor to a water mol-ecule. The hydr-oxy group on the benzohydrazide group is a hydrogen-bond donor to one acceptor site, whereas each water mol-ecule is a hydrogen-bond donor to two acceptor sites.

| S-EPMC2962201 | biostudies-literature

N'-(3-Bromo-5-chloro-2-hydroxy-benzyl-idene)-2-chloro-benzohydrazide methanol solvate.

Project description:In the title compound, C(14)H(9)BrCl(2)N(2)O(2)·CH(4)O, the dihedral angle between the two benzene rings is 49.2 (2)° and an intra-molecular O-H⋯N hydrogen bond occurs. In the crystal struture, mol-ecules are linked by O-H⋯O and N-H⋯O hydrogen bonds.

| S-EPMC2968918 | biostudies-literature

N'-(5-Chloro-2-hydroxy-benzyl-idene)-3,4,5-trihydroxy-benzohydrazide dihydrate.

Project description:The benzohydrazide mol-ecule in the title dihydrate, C(14)H(11)ClN(2)O(5)·2H(2)O, is non-planar, with the two aromatic rings at either side of the -C(=O)-NH-N=CH- unit forming a dihedral angle of 29.7?(2)°. The benzohydrazide mol-ecule is linked to the water mol-ecules by O-H?O and N-H?O hydrogen bonds, with other O-H?O hydrogen bonds leading to a layer structure.

| S-EPMC2968776 | biostudies-literature

N'-(2-Bromo-benzyl-idene)-3,4,5-tri-methoxy-benzohydrazide methanol solvate.

Project description:The title compound, C(17)H(17)BrN(2)O(4)·CH(4)O, was synthesized by the condensation of 3,4,5-trimethoxy-benzohydrazide and 2-bromo-benzaldehyde. The two aromatic rings are approximately planar, the dihedral angle being 3.08 (9)°. The mol-ecules are linked by inter-molecular N-H⋯O and O-H⋯O hydrogen bonds into chains along the a axis.

| S-EPMC2962239 | biostudies-literature

N'-(2-Chloro-benzyl-idene)-3,4,5-tri-methoxy-benzohydrazide methanol solvate.

Project description:In the title compound, C(17)H(17)ClN(2)O(4)·CH(4)O, the dihedral angle between the benzene ring planes is 5.29 (6)°. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the mol-ecules into a chain along the a axis.

| S-EPMC2962188 | biostudies-literature

N'-(2,4-Dimethoxy-benzyl-idene)-3,4,5-trihydroxy-benzohydrazide ethanol solvate.

Project description:The title compound, C(16)H(16)N(2)O(6)·C(2)H(5)OH, was synthesized from 3,4,5-trihydroxy-benzoyl-hydrazide and 2,4-dimethoxy-benzaldehyde in ethanol. The compound is not planar, with the two aromatic planes of the two aromatic rings twisted by 15.6?(1)°. The hydr-oxy groups are involved in both intra-molecular O-H?O and inter-molecular O-H?N and O-H?O hydrogen bonds and a C-H?O interaction also occurs.

| S-EPMC2969598 | biostudies-literature

3-Bromo-N'-(3,5-dibromo-2-hydroxy-benzyl-idene)benzohydrazide methanol solvate.

Project description:The title compound, C(14)H(9)Br(3)N(2)O(2)·CH(4)O, was prepared by the reaction of 3,5-dibromo-2-hydroxy-benzaldehyde and 3-bromo-benzohydrazide in methanol. The asymmetric unit of the crystal consists of a Schiff base mol-ecule and a methanol mol-ecule of crystallization. The dihedral angle between the two benzene rings is 5.5 (2)°. An intra-molecular O-H⋯N hydrogen bond is observed. In the crystal structure, pairs of adjacent Schiff base mol-ecules are linked by two methanol mol-ecules through inter-molecular N-H⋯O and O-H⋯O hydrogen bonds.

| S-EPMC2968809 | biostudies-literature

N'-(2-Chloro-5-nitro-benzyl-idene)-3-hydroxy-benzohydrazide methanol solvate.

Project description:In the title compound, C(14)H(10)ClN(3)O(4)·CH(3)OH, the dihedral angle between the two benzene rings is 33.9 (2)°. In the crystal structure, the methanol solvent mol-ecules are linked to the Schiff base mol-ecules through inter-molecular N-H⋯O and O-H⋯O hydrogen bonds. Mol-ecules are further linked through inter-molecular O-H⋯O and O-H⋯N hydrogen bonds, forming chains running along the b axis.

| S-EPMC2962016 | biostudies-literature

2-Chloro-N'-(3,5-dibromo-2-hydroxy-benzyl-idene)benzohydrazide methanol solvate.

Project description:The title Schiff base compound, C(14)H(9)Br(2)ClN(2)O(2)·CH(4)O, was derived from the condensation reaction of 3,5-dibromo-salicylaldehyde with 2-chloro-benzohydrazide. The dihedral angle between the two benzene rings is 48.2 (2)°. In the crystal structure, mol-ecules are linked through O-H⋯O and N-H⋯O inter-molecular hydrogen bonds, forming layers parallel to the bc plane. There is also an O-H⋯N intramolecular hydrogen bond.

| S-EPMC2962015 | biostudies-literature

N'-[1-(5-Bromo-2-hydroxy-phen-yl)ethyl-idene]-3,4,5-trihydroxy-benzohydrazide dimethyl sulfoxide solvate trihydrate.

Project description:The benzohydrazide mol-ecule in the title compound, C(15)H(13)BrN(2)O(5)·C(2)H(6)OS·3H(2)O, is almost planar with an r.m.s. deviation for the non-H atoms of 0.078 Å. The organic mol-ecules, water and dimethyl sulfoxide solvent mol-ecules are linked by N-H⋯O, O-H⋯O and O-H⋯S inter-molecular hydrogen bonds, forming zigzag chains along the a axis. Intra-molecular O-H⋯O and O-H⋯N hydrogen bonds also occur.

| S-EPMC2983555 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data