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Methyl 2-[2-((Z)-{1-trans-[2-(4-fluoro-3-methyl-phen-yl)-2-methyl-cyclo-prop-yl]ethyl-idene}amino-oxymeth-yl)phen-yl]-2-[(E)-methoxy-imino]-acetate.

ABSTRACT: The title compound, C(24)H(27)FN(2)O(4), is an important inter-mediate in the synthesis of fungicidal strobilurin-type compounds. In the crystal structure, the oxime bond attached to the cyclo-propane ring adopts a Z configuration, while the oxime bond attached to the benzene ring adopts an E configuration. The fluoro-methyl-phenyl group adopts a trans configuration with respect to the remainder of the mol-ecule, and its mean plane forms a dihedral angle of 56.1 (1)° with the plane of the cyclo-propane ring.

SUBMITTER: Song C

PROVIDER: S-EPMC2968980 | biostudies-literature |

REPOSITORIES: biostudies-literature

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4-[(E)-(3-Chloro-4-methyl-phen-yl)imino-meth-yl]-2-methoxy-3-nitro-phenyl acetate.

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3-(2-Fluoro-phen-yl)-1-(4-methoxy-phen-yl)prop-2-en-1-one.

Project description:The title compound, C(16)H(13)FO(2), was prepared from 4-methoxy-hypnone and 2-fluoro-benzophenone by a Claisen-Schmidt condensation reaction. The dihedral angle between the two benzene rings is 31.99 (2)°. In the crystal structure, mol-ecules are linked by weak inter-molecular C-H⋯O hydrogen bonds along [010].

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3-(4-Fluoro-phen-yl)-1-(4-methoxy-phen-yl)prop-2-en-1-one.

Project description:The title compound, C(16)H(13)FO(2), was prepared from 4-methoxy-hypnone and 4-fluoro-benzophenone by Claisen-Schmidt condensation. All the bond lengths and bond angles are in normal ranges. The dihedral angle formed by the two benzene rings is 33.49 (2)°. The crystal packing is stabilized by inter-molecular C-H⋯O hydrogen-bonding inter-actions.

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Project description:The title compound, C(13)H(16)N(2)O(3), adopts an E configuration with respect to the C=N bond and an intra-molecular N-H?N hydrogen bond results in the formation of a six-membered ring. In the crystal, inter-molecular O-H?O hydrogen bonds link the mol-ecules into a chain propagating along the b axis. Very weak ?-? stacking inter-actions [centroid-centroid distance = 4.18?(2)?Å] may further consolidate the packing, forming a two-dimensional supra-molecular network.

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(E)-1-(4-Fluoro-phen-yl)-3-(4-methyl-phen-yl)prop-2-en-1-one.

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4-(4-Fluoro-phen-yl)-1-methoxy-methyl-2-phenyl-1H-imidazole.

Project description:In the crystal structure of the title compound, C(17)H(15)FN(2)O, the mol-ecules form a three-dimensional network stabilized by ?-? inter-actions between two imidazole rings related by a centre of symmetry. The distance between the centroids is 3.5488?(8)?Å. The imidazole ring makes dihedral angles of 14.30?(7) and 33.39?(7)° with the 4-fluoro-phenyl ring and the phenyl ring, respectively.

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(E)-3-(4-Fluoro-phen-yl)-1-[4-(methyl-sulfan-yl)phen-yl]prop-2-en-1-one.

Project description:In the title mol-ecule, C(16)H(13)FOS, the dihedral angle between the two benzene rings is 8.68 (6)°. The H atoms of the central enone group are trans and one H atom is involved in a close intra-molecular C-H⋯O contact. The crystal structure is stabilized by weak C-H⋯π inter-actions.

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Project description:The title compound, C(14)H(13)Cl(2)NO(3), was obtained as the product of an attempted synthesis of herbicidally active compounds containing oxime ether and cyclo-hexenone groups. In the crystal structure, the mol-ecule adopts an endocyclic enol tautomeric form and the cyclo-hexene ring adopts a distorted envelope form. The oxime ether group has an E configuration, with the meth-oxy group anti to the ortho-chloro substitutent. Intra-molecular O-H?O and inter-molecular C-H?O hydrogen bonds are found in the crystal structure.

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