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Bis(?-penta-methyl-cyclo-penta-dien-yl)cobalt(II).

ABSTRACT: The crystal structure of the title compound, deca-methyl-cobaltocene, [Co(C(10)H(15))(2)], has been determined. High-quality single crystals were grown from a cold saturated hexa-methyl-disiloxane solution. The structure is related to the manganese and iron analogs. The molecule has D(5d) symmetry, with the Co atom in a crystallographic 2/m position. The cobalt-centroid(C(5)) distance is 1.71Å and the centroid(C(5))-Co-centroid(C(5)) angle is 180°, by symmetry.

SUBMITTER: Clark MM

PROVIDER: S-EPMC2969061 | biostudies-literature | 2009 Mar

REPOSITORIES: biostudies-literature

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Bis(η-penta-methyl-cyclo-penta-dien-yl)cobalt(II).

Clark Meghan M MM Brennessel William W WW Holland Patrick L PL

Acta crystallographica. Section E, Structure reports online 20090311 Pt 4

The crystal structure of the title compound, deca-methyl-cobaltocene, [Co(C(10)H(15))(2)], has been determined. High-quality single crystals were grown from a cold saturated hexa-methyl-disiloxane solution. The structure is related to the manganese and iron analogs. The molecule has D(5d) symmetry, with the Co atom in a crystallographic 2/m position. The cobalt-centroid(C(5)) distance is 1.71Å and the centroid(C(5))-Co-centroid(C(5)) angle is 180°, by symmetry. ...[more]

PMID: 21582340

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