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(±)-syn-Isopropyl 4-(1,1,1,3,3,3-hexa-fluoro-propan-2-yl-oxy)-1-hydr-oxy-3-methyl-2-(prop-1-yn-yl)cyclo-pent-2-ene-carboxyl-ate.


ABSTRACT: The title compound, C(16)H(18)F(6)O(4), was obtained through an unprecedented one-pot reaction sequence involving a Gosteli-Claisen rearrangement and a cyclo-isomerization. The constitution and relative configuration were determined by single-crystal X-ray diffraction analysis. In the crystal, mol-ecules are connected via O-H ? O hydrogen bonds.

SUBMITTER: Gille A 

PROVIDER: S-EPMC2969198 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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(±)-syn-Isopropyl 4-(1,1,1,3,3,3-hexa-fluoro-propan-2-yl-oxy)-1-hydr-oxy-3-methyl-2-(prop-1-yn-yl)cyclo-pent-2-ene-carboxyl-ate.

Gille Annika A   Schürmann Markus M   Preut Hans H   Hiersemann Martin M  

Acta crystallographica. Section E, Structure reports online 20090620 Pt 7


The title compound, C(16)H(18)F(6)O(4), was obtained through an unprecedented one-pot reaction sequence involving a Gosteli-Claisen rearrangement and a cyclo-isomerization. The constitution and relative configuration were determined by single-crystal X-ray diffraction analysis. In the crystal, mol-ecules are connected via O-H ⋯ O hydrogen bonds. ...[more]

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