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4-Methyl-3-nitro-pyridin-2-amine.

ABSTRACT: In the title compound, C(6)H(7)N(3)O(2), the dihedral angle between the nitro group and the pyridine ring is 15.5?(3)° and an intra-molecular N-H?O hydrogen bond occurs. In the crystal, inversion dimers linked by two N-H?N hydrogen bonds occur, resulting in R(2) (2)(8) rings. The packing is stabilized by aromatic ?-? stacking [centroid-centroid distance = 3.5666?(15)?Å] and a short N-O?? contact is seen.

SUBMITTER: Khan MA

PROVIDER: S-EPMC2969271 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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4-Methyl-3-nitro-pyridin-2-amine.

Khan Misbahul Ain MA Tahir M Nawaz MN Ather Abdul Qayyum AQ Shaheen Maryam M Khan Rauf Ahmad RA

Acta crystallographica. Section E, Structure reports online 20090620 Pt 7

In the title compound, C(6)H(7)N(3)O(2), the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intra-molecular N-H⋯O hydrogen bond occurs. In the crystal, inversion dimers linked by two N-H⋯N hydrogen bonds occur, resulting in R(2) (2)(8) rings. The packing is stabilized by aromatic π-π stacking [centroid-centroid distance = 3.5666 (15) Å] and a short N-O⋯π contact is seen. ...[more]

PMID: 21582886

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N-(4-Methyl-phen-yl)-3-nitro-pyridin-2-amine.

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