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[(2,3,5,6-?)-Bicyclo-[2.2.1]hepta-2,5-diene]dibromidopalladium(II).

ABSTRACT: In the title complex, [PdBr(2)(C(7)H(8))], the Pd(II) ion lies in a distorted square-planar environment defined by the two Br atoms and the mid-points of the two ?-coordinated double bonds of bicyclo-[2.2.1]hepta-2,5-diene. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through the Pd, Br atoms and the centre of the diene ligand.

SUBMITTER: Kim NH

PROVIDER: S-EPMC2969277 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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[(2,3,5,6-η)-Bicyclo-[2.2.1]hepta-2,5-diene]dibromidopalladium(II).

Kim Nam-Ho NH Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

In the title complex, [PdBr(2)(C(7)H(8))], the Pd(II) ion lies in a distorted square-planar environment defined by the two Br atoms and the mid-points of the two π-coordinated double bonds of bicyclo-[2.2.1]hepta-2,5-diene. The complex is disposed about a crystallographic mirror plane parallel to the ac plane passing through the Pd, Br atoms and the centre of the diene ligand. ...[more]

PMID: 21582670

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(?-Cyclo-penta-dien-yl){[3-(2,2-dicyano-ethen-yl)bicyclo-[2.2.1]hepta-2,5-dien-2-yl]ethyn-yl}(triphenyl-phosphine)nickel(II).

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(1S,4S)-2-(2,4-Difluoro-phen-yl)-5-[(4-methyl-phen-yl)sulfon-yl]-2,5-diaza-bicyclo-[2.2.1]hepta-ne.

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7-Iso-propyl-idene-N (2),N (3),N (5),N (6)-tetra-meth-oxy-N (2),N (3),N (5),N (6)-tetra-methylbi-cyclo-[2.2.1]hepta-2,5-diene-2,3,5,6-tetra-carboxamide.

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Regioselective palladium-catalyzed ring-opening reactions of C1-substituted oxabicyclo[2,2,1]hepta-2,5-diene-2,3-dicarboxylates.

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Bicyclo-[2.2.1]hept-7-yl p-bromo-benzoate.

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Bicyclo-[2.2.2]oct-7-ene-2,3,5,6-tetra-carboxylic dianhydride.

Project description:In the title compound, C(12)H(8)O(6), mol-ecules are linked by weak C-H?O inter-actions involving all the potential donors, generating a three-dimensional network.

| S-EPMC2961621 | biostudies-literature

2,5-Dichloro-3,6-diisopropyl-cyclo-hexa-2,5-diene-1,4-dione.

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