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Tetra-kis[3,5-bis-(trifluoro-meth-yl)phenyl]tin(IV).

ABSTRACT: The title mol-ecule, [Sn(C(8)H(3)F(6))(4)], lies on a twofold rotation axis with the Sn(IV) ion in a distorted tetra-hedral coordination environment. Both -CF(3) groups attached to one of the unique benzene rings are disordered over two sets of sites, with the ratios of refined occupancies being 0.719?(14):0.281?(14) and 0.63?(5):0.37?(5).

SUBMITTER: Foucher D

PROVIDER: S-EPMC2969316 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Tetra-kis[3,5-bis-(trifluoro-meth-yl)phenyl]tin(IV).

Foucher Daniel D Miles Damion D Lough Alan J AJ

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

The title mol-ecule, [Sn(C(8)H(3)F(6))(4)], lies on a twofold rotation axis with the Sn(IV) ion in a distorted tetra-hedral coordination environment. Both -CF(3) groups attached to one of the unique benzene rings are disordered over two sets of sites, with the ratios of refined occupancies being 0.719 (14):0.281 (14) and 0.63 (5):0.37 (5). ...[more]

PMID: 21582650

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