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Dichlorido[tris-(1H-benzimidazol-2-ylmeth-yl)amine-?N,N,N,N]iron(III) chloride tetra-hydro-furan monosolvate monohydrate.

ABSTRACT: In the title compound, [FeCl(2)(C(24)H(21)N(7))]Cl·C(4)H(8)O·H(2)O, the Fe(III) atom is coordinated by four N atoms of the polybenzimidazole ligand and two Cl atoms in a distorted octa-hedral environment. The cation, anion, the uncoordinated water mol-ecule and the THF solvent molecule are linked by hydrogen bonds into a three-dimensional network structure. The THF molecule is disordered with two sets of sites in a 0.58?(1):0.42?(2) ratio..

SUBMITTER: Wang D

PROVIDER: S-EPMC2969328 | biostudies-literature | 2009

REPOSITORIES: biostudies-literature

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Dichlorido[tris-(1H-benzimidazol-2-ylmeth-yl)amine-κN,N,N,N]iron(III) chloride tetra-hydro-furan monosolvate monohydrate.

Wang Dong'e D

Acta crystallographica. Section E, Structure reports online 20090627 Pt 7

In the title compound, [FeCl(2)(C(24)H(21)N(7))]Cl·C(4)H(8)O·H(2)O, the Fe(III) atom is coordinated by four N atoms of the polybenzimidazole ligand and two Cl atoms in a distorted octa-hedral environment. The cation, anion, the uncoordinated water mol-ecule and the THF solvent molecule are linked by hydrogen bonds into a three-dimensional network structure. The THF molecule is disordered with two sets of sites in a 0.58 (1):0.42 (2) ratio.. ...[more]

PMID: 21582746

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