Unknown

Dataset Information

0

Ni(2)Si(P(2)O(7))(2).


ABSTRACT: Dinickel(II) silicon bis-[diphosphate(4-)], Ni(2)Si(P(2)O(7))(2), is isotypic with other phosphates of the formula M(2)Si(P(2)O(7))(2) (M = Co, Cd). All atoms except Si (site symmetry 2) are found in general positions. Ni(2)O(10) dimers formed from edge-sharing NiO(6) octa-hedra are linked by corners and O-P-O bridges, forming slabs parallel to (100), which are in turn inter-connected by O-Si-O contacts.

SUBMITTER: Toubi Y 

PROVIDER: S-EPMC2969362 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

altmetric image

Publications

Ni(2)Si(P(2)O(7))(2).

Toubi Yahya Y   Essehli Rachid R   Dušek Michal M   Fejfarová Karla K   El Bali Brahim B  

Acta crystallographica. Section E, Structure reports online 20090627 Pt 7


Dinickel(II) silicon bis-[diphosphate(4-)], Ni(2)Si(P(2)O(7))(2), is isotypic with other phosphates of the formula M(2)Si(P(2)O(7))(2) (M = Co, Cd). All atoms except Si (site symmetry 2) are found in general positions. Ni(2)O(10) dimers formed from edge-sharing NiO(6) octa-hedra are linked by corners and O-P-O bridges, forming slabs parallel to (100), which are in turn inter-connected by O-Si-O contacts. ...[more]

Similar Datasets

| S-EPMC6650849 | biostudies-literature
| S-EPMC6515224 | biostudies-literature
| S-EPMC4614450 | biostudies-other
| S-EPMC7254276 | biostudies-literature
| S-EPMC4314467 | biostudies-literature
| S-EPMC7124930 | biostudies-literature
| S-EPMC4046995 | biostudies-literature
| S-EPMC9609945 | biostudies-literature
| S-EPMC4484491 | biostudies-literature
| S-EPMC8281251 | biostudies-literature