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Dibromidobis(1,10-phenanthroline-?N,N')cadmium(II).

ABSTRACT: The title compound, [CdBr(2)(C(12)H(8)N(2))(2)], synthesized by the hydro-thermal reaction of Cd(CH(3)COO)(2)·2H(2)O with NaBr and 1,10-phenanthroline, has the Cd(II) cation coordinated by two Br(-) anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The crystal packing is stabilized by inter-molecular ?-? inter-actions with centroid-centroid distances 3.572?(1) and 3.671?(1)?Å together with C-H?Br hydrogen bonds.

SUBMITTER: Sun YH

PROVIDER: S-EPMC2969372 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Dibromidobis(1,10-phenanthroline-κN,N')cadmium(II).

Sun Yu-Hui YH Luo Shu-Fen SF Zhang Xiu-Zhi XZ Du Zi-Yi ZY

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

The title compound, [CdBr(2)(C(12)H(8)N(2))(2)], synthesized by the hydro-thermal reaction of Cd(CH(3)COO)(2)·2H(2)O with NaBr and 1,10-phenanthroline, has the Cd(II) cation coordinated by two Br(-) anions and four N atoms from two 1,10-phenanthroline ligands in a distorted octa-hedral geometry. The crystal packing is stabilized by inter-molecular π-π inter-actions with centroid-centroid distances 3.572 (1) and 3.671 (1) Å together with C-H⋯Br hydrogen bonds. ...[more]

PMID: 21582654

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