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Bis(triphenyl-stann-yl) thio-phene-2,5-dicarboxyl-ate.

ABSTRACT: Mol-ecules of the title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(2)O(4)S)], lie on inversion centres with the central thio-phene ring disordered equally over two orientations. The carboxyl-ate groups are approximately coplanar with the thio-phene ring [dihedral angle = 4.0?(1)°] and the Sn-O bond distance of 2.058?(4)?Å is comparable to that in related organotin carboxyl-ates.

SUBMITTER: Zhao L

PROVIDER: S-EPMC2969381 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Bis(triphenyl-stann-yl) thio-phene-2,5-dicarboxyl-ate.

Zhao Lichun L Liang Jian J Yue Guihua G Deng Xin X He Ying Y

Acta crystallographica. Section E, Structure reports online 20090606 Pt 7

Mol-ecules of the title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(2)O(4)S)], lie on inversion centres with the central thio-phene ring disordered equally over two orientations. The carboxyl-ate groups are approximately coplanar with the thio-phene ring [dihedral angle = 4.0 (1)°] and the Sn-O bond distance of 2.058 (4) Å is comparable to that in related organotin carboxyl-ates. ...[more]

PMID: 21582666

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