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2-All-yloxy-5-nitro-benzoic acid.

ABSTRACT: The mol-ecule of the title compound, C(10)H(9)NO(5), is approximately planar, with the mean planes of the nitro, carboxyl and all-yloxy groups rotated by 8.1?(3), 7.9?(3) and 4.52?(18)°, respectively, from the plane of the benzene ring. Bond lengths in the aromatic ring are influenced by both electronic effects and strain induced by ortho-substitution. In the crystal structure, centrosymmetrically related mol-ecules are paired into dimers through strong O-H?O hydrogen bonds.

SUBMITTER: Ferreira VB

PROVIDER: S-EPMC2969386 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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2-All-yloxy-5-nitro-benzoic acid.

Ferreira Valquiria B N VB Fiedler Haidi D HD Nome Faruk F Bortoluzzi Adailton J AJ

Acta crystallographica. Section E, Structure reports online 20090627 Pt 7

The mol-ecule of the title compound, C(10)H(9)NO(5), is approximately planar, with the mean planes of the nitro, carboxyl and all-yloxy groups rotated by 8.1 (3), 7.9 (3) and 4.52 (18)°, respectively, from the plane of the benzene ring. Bond lengths in the aromatic ring are influenced by both electronic effects and strain induced by ortho-substitution. In the crystal structure, centrosymmetrically related mol-ecules are paired into dimers through strong O-H⋯O hydrogen bonds. ...[more]

PMID: 21582969

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