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Chloridobis(ethyl-enediamine-?N,N')(n-pentyl-amine-?N)cobalt(III) dichloride monhydrate.

ABSTRACT: The title complex, [CoCl(C(5)H(13)N)(C(2)H(8)N(2))(2)]Cl(2)·H(2)O, comprises one chloridobis(ethyl-enediamine)(n-pentyl-amine)cobalt(III) cation, two chloride counter-anions and a water mol-ecule. The Co(III) atom of the complex is hexa-coordinated by five N and one Cl atoms. The five N atoms are from two chelating ethyl-enediamine and one n-pentyl-amine ligands. Neighbouring cations and anions are connected by N-H?Cl and N-H?O hydrogen bonds to each other and also to the water mol-ecule.

SUBMITTER: Anbalagan K 

PROVIDER: S-EPMC2969482 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Chloridobis(ethyl-enediamine-κN,N')(n-pentyl-amine-κN)cobalt(III) dichloride monhydrate.

Anbalagan K K   Tamilselvan M M   Nirmala S S   Sudha L L  

Acta crystallographica. Section E, Structure reports online 20090627 Pt 7

The title complex, [CoCl(C(5)H(13)N)(C(2)H(8)N(2))(2)]Cl(2)·H(2)O, comprises one chloridobis(ethyl-enediamine)(n-pentyl-amine)cobalt(III) cation, two chloride counter-anions and a water mol-ecule. The Co(III) atom of the complex is hexa-coordinated by five N and one Cl atoms. The five N atoms are from two chelating ethyl-enediamine and one n-pentyl-amine ligands. Neighbouring cations and anions are connected by N-H⋯Cl and N-H⋯O hydrogen bonds to each other and also to the water mol-ecule. ...[more]

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