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6-Bromo-3,3-dichloro-1-methyl-1H-2,1-benzothia-zin-4(3H)-one 2,2-dioxide.

ABSTRACT: The monomeric title compound, C(9)H(6)BrCl(2)NO(3)S, has an envelope-shaped thia-zine ring with the S atom 0.879?(9)?Å out of the mean square plane of the envelope. The ?-? distances between the centroids of the heterocyclic rings are 4.191?(5) and 4.110?(5)?Å. The closest intermolecular inter-actions between the O atoms of the carbonyl and sulfonyl groups with Br and Cl atoms are 2.987?(7) and 2.992?(8)?Å, respectively.

SUBMITTER: Shafiq M

PROVIDER: S-EPMC2969529 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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6-Bromo-3,3-dichloro-1-methyl-1H-2,1-benzothia-zin-4(3H)-one 2,2-dioxide.

Shafiq Muhammad M Tahir M Nawaz MN Khan Islam Ullah IU Arshad Muhammad Nadeem MN Haider Zeeshan Z

Acta crystallographica. Section E, Structure reports online 20090529 Pt 6

The monomeric title compound, C(9)H(6)BrCl(2)NO(3)S, has an envelope-shaped thia-zine ring with the S atom 0.879 (9) Å out of the mean square plane of the envelope. The π-π distances between the centroids of the heterocyclic rings are 4.191 (5) and 4.110 (5) Å. The closest intermolecular inter-actions between the O atoms of the carbonyl and sulfonyl groups with Br and Cl atoms are 2.987 (7) and 2.992 (8) Å, respectively. ...[more]

PMID: 21583256

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