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2,2'-{1,1'-[Butane-1,4-diyl-bis(oxy-nitrilo)]di-ethylidyne}di-1-naphthol.

ABSTRACT: The title compound, C(28)H(28)N(2)O(4), was synthesized by the reaction of 2-acetyl-1-naphthol with 1,4-bis-(amino-oxy)butane in ethanol. The molecule, which lies about an inversion centre, adopts a linear structure, in which the oxime groups and naphthalene ring systems assume an anti conformation. The intra-molecular inter-planar distance between parallel naphthalene rings is 1.054?(3)?Å. Intra-molecular O-H?N hydrogen bonds are formed between the oxime nitro-gen and hydr-oxy groups.

SUBMITTER: Dong WK

PROVIDER: S-EPMC2969537 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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2,2'-{1,1'-[Butane-1,4-diyl-bis(oxy-nitrilo)]di-ethylidyne}di-1-naphthol.

Dong Wen-Kui WK Wu Jian-Chao JC Sun Yin-Xia YX Yao Jian J Tong Jun-Feng JF

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

The title compound, C(28)H(28)N(2)O(4), was synthesized by the reaction of 2-acetyl-1-naphthol with 1,4-bis-(amino-oxy)butane in ethanol. The molecule, which lies about an inversion centre, adopts a linear structure, in which the oxime groups and naphthalene ring systems assume an anti conformation. The intra-molecular inter-planar distance between parallel naphthalene rings is 1.054 (3) Å. Intra-molecular O-H⋯N hydrogen bonds are formed between the oxime nitro-gen and hydr-oxy groups. ...[more]

PMID: 21583113

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