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Poly[(?(2)-azido-?N:N)[?(2)-5-(8-quinolyl-oxy-methyl)tetra-zolato-?N,O,N:N]zinc(II)].

ABSTRACT: In the title compound, [Zn(C(11)H(8)N(5)O)(N(3))](n), the Zn atom is hexa-coordinated by five N atoms and one O atom in a distorted octa-hedral geometry. The chelating 5-(8-quinolyloxymeth-yl)tetra-zolate ligands are approximately planar, with a dihedral angle of 3.6?(2)° between the quinoline and tetra-zole planes. Adjacent Zn atoms are linked by two bridging azide ligands across a centre of inversion, and further coordination by one N atom of an adjacent tetra-zole unit forms two-dimensional frameworks in (100). C-H?N inter-actions exist between ligands in neighbouring layers.

SUBMITTER: Cai HL

PROVIDER: S-EPMC2969550 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Poly[(μ(2)-azido-κN:N)[μ(2)-5-(8-quinolyl-oxy-methyl)tetra-zolato-κN,O,N:N]zinc(II)].

Cai Hong-Ling HL

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

In the title compound, [Zn(C(11)H(8)N(5)O)(N(3))](n), the Zn atom is hexa-coordinated by five N atoms and one O atom in a distorted octa-hedral geometry. The chelating 5-(8-quinolyloxymeth-yl)tetra-zolate ligands are approximately planar, with a dihedral angle of 3.6 (2)° between the quinoline and tetra-zole planes. Adjacent Zn atoms are linked by two bridging azide ligands across a centre of inversion, and further coordination by one N atom of an adjacent tetra-zole unit forms two-dimensional f ...[more]

PMID: 21583000

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