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ABSTRACT:
SUBMITTER: Chang CP
PROVIDER: S-EPMC2969551 | biostudies-literature | 2009 May
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20090520 Pt 6
In the title complex, [CoPd(2)(C(3)H(5))(2)(C(8)H(11))Cl(2)(C(40)H(30)P(2))]·CH(2)Cl(2), the Co(I) atom is sandwiched between the cyclo-penta-dienyl and cyclo-butadiene rings. The two diphenyl-phosphine substituents of the cyclo-butadiene ring are situated opposite to each other and bind two Pd(II) atoms, which are additionally coordinated by a chloride ion and the three C atoms of an allyl ligand, forming a distorted planar coordination environment. The Cl atoms of the dichloro-methane solvent ...[more]