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Bis[1,3(?)-all-yl][?-2(?)-1,3-bis-(di-phenyl-phosphino)-2,4-diphenyl-cyclo-buta-1,3-diene-1:3?P:P']dichlorido-1?Cl,3?Cl-[2(?)-isopropyl-cyclo-penta-dien-yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro-methane solvate.

ABSTRACT: In the title complex, [CoPd(2)(C(3)H(5))(2)(C(8)H(11))Cl(2)(C(40)H(30)P(2))]·CH(2)Cl(2), the Co(I) atom is sandwiched between the cyclo-penta-dienyl and cyclo-butadiene rings. The two diphenyl-phosphine substituents of the cyclo-butadiene ring are situated opposite to each other and bind two Pd(II) atoms, which are additionally coordinated by a chloride ion and the three C atoms of an allyl ligand, forming a distorted planar coordination environment. The Cl atoms of the dichloro-methane solvent mol-ecule (equal occupancies) and one C atom and its attached H atom of each of the allyl ligands (occupancies 0.55:0.45) are disordered.

SUBMITTER: Chang CP 

PROVIDER: S-EPMC2969551 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Bis[1,3(η)-all-yl][μ-2(η)-1,3-bis-(di-phenyl-phosphino)-2,4-diphenyl-cyclo-buta-1,3-diene-1:3κP:P']dichlorido-1κCl,3κCl-[2(η)-isopropyl-cyclo-penta-dien-yl]-2-cobalt(I)-1,3-dipalladium(II) dichloro-methane solvate.

Chang Chin-Pei CP   Hong Fung-E FE  

Acta crystallographica. Section E, Structure reports online 20090520 Pt 6

In the title complex, [CoPd(2)(C(3)H(5))(2)(C(8)H(11))Cl(2)(C(40)H(30)P(2))]·CH(2)Cl(2), the Co(I) atom is sandwiched between the cyclo-penta-dienyl and cyclo-butadiene rings. The two diphenyl-phosphine substituents of the cyclo-butadiene ring are situated opposite to each other and bind two Pd(II) atoms, which are additionally coordinated by a chloride ion and the three C atoms of an allyl ligand, forming a distorted planar coordination environment. The Cl atoms of the dichloro-methane solvent  ...[more]

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