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(?-Cyclo-penta-dien-yl)(?-mesitylamine)ruthenium(II) hexa-fluorido-phosphate.

ABSTRACT: The title compound, [Ru(?(5)-C(5)H(5)){?(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107?(3)?Å from the least-squares plane of the remaining five benzene ring atoms, which show an r.m.s. deviation of 0.005?Å. N-H?F hydrogen-bonding interactions help to consolidate the crystal packing.

SUBMITTER: Becker E

PROVIDER: S-EPMC2969571 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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(η-Cyclo-penta-dien-yl)(η-mesitylamine)ruthenium(II) hexa-fluorido-phosphate.

Becker Eva E Kirchner Karl K Mereiter Kurt K

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

The title compound, [Ru(η(5)-C(5)H(5)){η(6)-C(6)H(2)(CH(3))(3)NH(2)}]PF(6), contains a sandwich complex with a mesitylamine unit which is significantly non-planar at the ipso-carbon of the amino group due to repulsive electronic effects with Ru. The ipso-carbon deviates by 0.107 (3) Å from the least-squares plane of the remaining five benzene ring atoms, which show an r.m.s. deviation of 0.005 Å. N-H⋯F hydrogen-bonding interactions help to consolidate the crystal packing. ...[more]

PMID: 21582999

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