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RbCa(2)Nb(3)O(10) from X-ray powder data.

ABSTRACT: Rubidium dicalcium triniobate(V), RbCa(2)Nb(3)O(10), has been synthesized by solid-state reaction and its crystal structure refined from X-ray powder diffraction data using Rietveld analysis. The compound is a three-layer perovskite Dion-Jacobson phase with the perovskite-like slabs derived by termination of the three-dimensional CaNbO(3) perovskite structure along the ab plane. The rubidium ions (4/mmm symmetry) are located in the inter-stitial space.

SUBMITTER: Liang ZH

PROVIDER: S-EPMC2969613 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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RbCa(2)Nb(3)O(10) from X-ray powder data.

Liang Zhen-Hua ZH Tang Kai-Bin KB Chen Qian-Wang QW Zheng Hua-Gui HG

Acta crystallographica. Section E, Structure reports online 20090523 Pt 6

Rubidium dicalcium triniobate(V), RbCa(2)Nb(3)O(10), has been synthesized by solid-state reaction and its crystal structure refined from X-ray powder diffraction data using Rietveld analysis. The compound is a three-layer perovskite Dion-Jacobson phase with the perovskite-like slabs derived by termination of the three-dimensional CaNbO(3) perovskite structure along the ab plane. The rubidium ions (4/mmm symmetry) are located in the inter-stitial space. ...[more]

PMID: 21582979

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