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(E)-2-[(3,5-Di-tert-butyl-2-hydroxy-benzyl-idene)amino]benzonitrile.

ABSTRACT: The asymmetric unit of the title compound, C(22)H(26)N(2)O, contains three crystallographically independent mol-ecules, in which the aromatic rings are oriented at dihedral angles of 21.74?(5), 27.59?(5) and 27.87?(5)°. Intra-molecular O-H?N hydrogen bonds result in the formation of planar six-membered rings, and these are nearly coplanar with the adjacent rings. In the crystal structure, ?-? contacts between the benzene rings [centroid-centroid distances = 3.989?(2), 3.802?(1) and 3.882?(1)?Å] may stabilize the structure.

SUBMITTER: Zhou JC 

PROVIDER: S-EPMC2969623 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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(E)-2-[(3,5-Di-tert-butyl-2-hydroxy-benzyl-idene)amino]benzonitrile.

Zhou Jian-Cheng JC   Li Nai-Xu NX   Zhang Chuan-Ming CM   Zhang Zheng-Yun ZY  

Acta crystallographica. Section E, Structure reports online 20090529 Pt 6

The asymmetric unit of the title compound, C(22)H(26)N(2)O, contains three crystallographically independent mol-ecules, in which the aromatic rings are oriented at dihedral angles of 21.74 (5), 27.59 (5) and 27.87 (5)°. Intra-molecular O-H⋯N hydrogen bonds result in the formation of planar six-membered rings, and these are nearly coplanar with the adjacent rings. In the crystal structure, π-π contacts between the benzene rings [centroid-centroid distances = 3.989 (2), 3.802 (1) and 3.882 (1) Å]  ...[more]

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