Unknown

Dataset Information

0

Tris{2-meth-oxy-6-[(4-methyl-phenyl)-iminiometh-yl]phenolato-?O,O'}tris-(thio-cyanato-?N)cerium(III).

ABSTRACT: The asymmetric unit of the title compound, [Ce(NCS)(3)(C(15)H(15)NO(2))(3)], contains three Schiff base 2-methoxy-6-[(4-methyl-phenyl)iminometh-yl]-phenol (HL) ligands and three independent thio-cyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved in an intra-molecular hydrogen bond with the respective phenoxide group. The Ce(III) ion exhibits a coordination number of nine.

SUBMITTER: Liu JF 

PROVIDER: S-EPMC2969666 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tris{2-meth-oxy-6-[(4-methyl-phenyl)-iminiometh-yl]phenolato-κO,O'}tris-(thio-cyanato-κN)cerium(III).

Liu Jian-Feng JF   Xian Hui-Duo HD   Zhao Guo-Liang GL  

Acta crystallographica. Section E, Structure reports online 20090514 Pt 6

The asymmetric unit of the title compound, [Ce(NCS)(3)(C(15)H(15)NO(2))(3)], contains three Schiff base 2-methoxy-6-[(4-methyl-phenyl)iminometh-yl]-phenol (HL) ligands and three independent thio-cyanate ions that coordinate the cerium ion via their N atoms. The protonated imine N atoms are involved in an intra-molecular hydrogen bond with the respective phenoxide group. The Ce(III) ion exhibits a coordination number of nine. ...[more]

Similar Datasets

Unknown Tris[6-meth-oxy-2-(phenyl-iminiometh-yl)phenolato]-?O,O';?O-tris-(thio-cyanato-?N)samarium(III).
| S-EPMC3120503 | biostudies-literature
Unknown Tris{2-meth-oxy-6-[(4-methyl-phen-yl)iminiometh-yl]phenolato-?O,O'}tris-(thio-cyanato-?N)praseodymium(III) monohydrate.
| S-EPMC2971403 | biostudies-literature
Unknown Tris[2-meth-oxy-6-(4-methyl-phenyl-iminio-meth-yl)phenolato-?O,O']tris-(thio-cyanato-?N)neodymium(III).
| S-EPMC2980016 | biostudies-literature
Unknown Tris{2-meth-oxy-6-[(4-methyl-phen-yl)iminiometh-yl]phenolate-?O,O'}tris-(thio-cyanato-?N)europium(III).
| S-EPMC2972108 | biostudies-literature
Unknown Tris{2-meth-oxy-6-[(4-methyl-phen-yl)iminiometh-yl]phenolate-κO,O'}tris-(thio-cyanato-κN)lanthanum(III).
| S-EPMC2971951 | biostudies-literature
Unknown (Methanol-?O)bis-{2-meth-oxy-6-[(4-methyl-phen-yl)iminiometh-yl]phenolato-?O,O'}tris-(nitrato-?O,O')cerium(III).
| S-EPMC3007323 | biostudies-literature
Unknown Bis(2-meth-oxy-6-{[2-(methyl-ammonio)eth-yl]imino-meth-yl}phenolato)thio-cyanato-zinc(II) thio-cyanate hemihydrate.
| S-EPMC2969465 | biostudies-literature
Unknown Bis{2-eth-oxy-6-[2-(methyl-ammonio)ethyl-imino-meth-yl]phenolato}thio-cyanato-zinc(II) nitrate.
| S-EPMC2979686 | biostudies-literature
Unknown Bis{2-meth-oxy-6-[(4-methyl-phen-yl)iminiometh-yl]phenolato-?O,O}tris-(nitrato-?O,O')methano-lsamarium(III).
| S-EPMC3051746 | biostudies-literature
Unknown {5-Meth-oxy-2-[(2-morpholinoethyl)-iminometh-yl]phenolato}(thio-cyanato-?N)-nickel(II).
| S-EPMC2983697 | biostudies-literature