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1-{2-[(4-Hydr-oxy-3-methoxy-benzyl-idene)amino]eth-yl}-3-methylimid-azolium hexa-fluoro-phosphate.

ABSTRACT: In the title Schiff base salt, C(14)H(18)N(3)O(2) (+)·PF(6) (-), the dihedral angle between the planes of the aromatic and imidazole rings is 24.84?(8)°. The mol-ecular structure exhibits an intra-molecular O-H?O hydrogen bond, which generates an S(5) ring motif. In the crystal structure, the cations and anions are connected via O-H?N and O-H?F hydrogen bonds, resulting in a trifurcated interaction for the phenolic H atom.

SUBMITTER: Li B

PROVIDER: S-EPMC2969671 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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1-{2-[(4-Hydr-oxy-3-methoxy-benzyl-idene)amino]eth-yl}-3-methylimid-azolium hexa-fluoro-phosphate.

Li Bin B Li Yi-Qun YQ Liu Jie J Zheng Wen-Jie WJ

Acta crystallographica. Section E, Structure reports online 20090529 Pt 6

In the title Schiff base salt, C(14)H(18)N(3)O(2) (+)·PF(6) (-), the dihedral angle between the planes of the aromatic and imidazole rings is 24.84 (8)°. The mol-ecular structure exhibits an intra-molecular O-H⋯O hydrogen bond, which generates an S(5) ring motif. In the crystal structure, the cations and anions are connected via O-H⋯N and O-H⋯F hydrogen bonds, resulting in a trifurcated interaction for the phenolic H atom. ...[more]

PMID: 21583268

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