Unknown

Dataset Information

0

Tetra-aqua-(1,10-phenanthroline-5,6-dione-?N,N')cobalt(II) dinitrate.

ABSTRACT: The asymmetric unit of the title compound, [Co(C(12)H(6)N(2)O(2))(H(2)O)(4)](NO(3))(2), consists of a Co(II) complex cation with twofold rotational symmetry and two nitrate anions. The Co(II) atom has a distorted octa-hedral geometry with the basal plane occupied by two 1,10-phenanthroline-5,6-dione N atoms and two aqua O atoms, with the other two aqua ligands in axial positions. The aqua ligands are involved in extensive hydrogen bonding to nitrate and 1,10-phenanthroline-5,6-dione O atoms.

SUBMITTER: Shi WJ 

PROVIDER: S-EPMC2969730 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Tetra-aqua-(1,10-phenanthroline-5,6-dione-κN,N')cobalt(II) dinitrate.

Shi Wen-Juan WJ  

Acta crystallographica. Section E, Structure reports online 20090520 Pt 6

The asymmetric unit of the title compound, [Co(C(12)H(6)N(2)O(2))(H(2)O)(4)](NO(3))(2), consists of a Co(II) complex cation with twofold rotational symmetry and two nitrate anions. The Co(II) atom has a distorted octa-hedral geometry with the basal plane occupied by two 1,10-phenanthroline-5,6-dione N atoms and two aqua O atoms, with the other two aqua ligands in axial positions. The aqua ligands are involved in extensive hydrogen bonding to nitrate and 1,10-phenanthroline-5,6-dione O atoms. ...[more]

Similar Datasets

Unknown Bis[tetra-aqua-(1,10-phenanthroline-?N,N')cobalt(II)] hexa-aqua-cobalt(II) bis-[3,5-bis-(carboxyl-atometh-oxy)benzoate] tetra-hydrate.
| S-EPMC3011475 | biostudies-literature
Unknown Dichloridobis(1,10-phenanthroline-5,6-dione-κN,N')mercury(II).
| S-EPMC2971919 | biostudies-literature
Unknown 1,10-Phenanthroline-5,6-dione ethanol monosolvate.
| S-EPMC4011276 | biostudies-literature
Unknown Tris(1,10-phenanthroline-?N,N')nickel(II) dinitrate tetra-hydrate.
| S-EPMC3238704 | biostudies-literature
Unknown Aqua-(hippurato)bis-(1,10-phenanthroline)cobalt(II) nitrate monohydrate.
| S-EPMC3009208 | biostudies-literature
Unknown An acetonitrile solvatomorph of di-chlorido-(1,10-phenanthroline-5,6-dione)platinum(II).
| S-EPMC4029211 | biostudies-literature
Unknown Acetato(1,10-phenanthroline-5,6-dione)silver(I) trihydrate.
| S-EPMC2960336 | biostudies-literature
Unknown Tetra-aqua-(1,10-phenanthroline-?N,N')cadmium(II) sulfate dihydrate.
| S-EPMC3007401 | biostudies-literature
Unknown A new polymorph of aqua-bis-(1,10-phenanthroline-?(2) N,N')copper(II) dinitrate.
| S-EPMC4011280 | biostudies-literature
Unknown Diiodido(1,10-phenanthroline-5,6-dione-?N,N')mercury(II).
| S-EPMC3201394 | biostudies-other