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Tetra-aqua-(1,10-phenanthroline-5,6-dione-?N,N')cobalt(II) dinitrate.

ABSTRACT: The asymmetric unit of the title compound, [Co(C(12)H(6)N(2)O(2))(H(2)O)(4)](NO(3))(2), consists of a Co(II) complex cation with twofold rotational symmetry and two nitrate anions. The Co(II) atom has a distorted octa-hedral geometry with the basal plane occupied by two 1,10-phenanthroline-5,6-dione N atoms and two aqua O atoms, with the other two aqua ligands in axial positions. The aqua ligands are involved in extensive hydrogen bonding to nitrate and 1,10-phenanthroline-5,6-dione O atoms.

SUBMITTER: Shi WJ

PROVIDER: S-EPMC2969730 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Tetra-aqua-(1,10-phenanthroline-5,6-dione-κN,N')cobalt(II) dinitrate.

Shi Wen-Juan WJ

Acta crystallographica. Section E, Structure reports online 20090520 Pt 6

The asymmetric unit of the title compound, [Co(C(12)H(6)N(2)O(2))(H(2)O)(4)](NO(3))(2), consists of a Co(II) complex cation with twofold rotational symmetry and two nitrate anions. The Co(II) atom has a distorted octa-hedral geometry with the basal plane occupied by two 1,10-phenanthroline-5,6-dione N atoms and two aqua O atoms, with the other two aqua ligands in axial positions. The aqua ligands are involved in extensive hydrogen bonding to nitrate and 1,10-phenanthroline-5,6-dione O atoms. ...[more]

PMID: 21583017

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