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Sodium N-chloro-2-methyl-benzene-sulfonamidate sesquihydrate.


ABSTRACT: In the title salt, Na(+)·C(7)H(7)ClNO(2)S(-)·1.5H(2)O, one of the water mol-ecules lies on a twofold axis. The sodium ion shows an O(6) octa-hedral coordination defined by three water O atoms and three sulfonyl O atoms derived from three different anions. The S-N distance of 1.5898?(19)?Å is consistent with an S=N double bond. The crystal structure is stabilized by N-H?O and O-H?Cl hydrogen bonds.

SUBMITTER: Gowda BT 

PROVIDER: S-EPMC2969781 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

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Sodium N-chloro-2-methyl-benzene-sulfonamidate sesquihydrate.

Gowda B Thimme BT   Foro Sabine S   Fuess Hartmut H  

Acta crystallographica. Section E, Structure reports online 20090529 Pt 6


In the title salt, Na(+)·C(7)H(7)ClNO(2)S(-)·1.5H(2)O, one of the water mol-ecules lies on a twofold axis. The sodium ion shows an O(6) octa-hedral coordination defined by three water O atoms and three sulfonyl O atoms derived from three different anions. The S-N distance of 1.5898 (19) Å is consistent with an S=N double bond. The crystal structure is stabilized by N-H⋯O and O-H⋯Cl hydrogen bonds. ...[more]

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