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[3-Bromo-2-(3-fluoro-benz-yloxy)phen-yl]boronic acid.

ABSTRACT: In the title compound, C(13)H(11)BBrFO(3), the dioxy-boron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intra-molecular O-H⋯O hydrogen-bonding inter-action. The second OH group is involved in inter-molecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two positions in a 0.675 (6):0.325 (6) ratio.

SUBMITTER: Kacprzak K 

PROVIDER: S-EPMC2969934 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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[3-Bromo-2-(3-fluoro-benz-yloxy)phen-yl]boronic acid.

Kacprzak Kinga K   Klis Tomasz T   Serwatowski Janusz J  

Acta crystallographica. Section E, Structure reports online 20090826 Pt 9

In the title compound, C(13)H(11)BBrFO(3), the dioxy-boron fragment is close to co-planar with the benzene ring to which the B atom is connected [dihedral angle = 8.96 (4)°]. The dihedral angle between the two benzene rings is 14.8 (2)°. One of the OH groups is engaged in an intra-molecular O-H⋯O hydrogen-bonding inter-action. The second OH group is involved in inter-molecular hydrogen bonding, forming a centrosymmetric dimer. The F atom and the corresponding meta-H atom are disordered over two  ...[more]

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