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(E)-N'-(3,5-Dibromo-2-hydroxy-benzyl-idene)-2-nitro-benzohydrazide methanol solvate.

ABSTRACT: In the title compound, C(14)H(9)Br(2)N(3)O(4)·CH(3)OH, the Schiff base mol-ecule adopts an E geometry with respect to the C=N bond and the benzene rings are oriented at a dihedral angle of 45.3 (2)°. An intra-molecular O-H⋯N hydrogen bond helps to establish the conformation. In the crystal, the methanol solvent mol-ecule is linked to the Schiff base mol-ecule through an O-H⋯O hydrogen bond and inter-molecular N-H⋯O hydrogen bonds link the components to form layers parallel to the bc direction.

SUBMITTER: Qian HY

PROVIDER: S-EPMC2969957 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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(E)-N'-(3,5-Dibromo-2-hydroxy-benzyl-idene)-2-nitro-benzohydrazide methanol solvate.

Qian Heng-Yu HY Qu Da-Ping DP

Acta crystallographica. Section E, Structure reports online 20090826 Pt 9

In the title compound, C(14)H(9)Br(2)N(3)O(4)·CH(3)OH, the Schiff base mol-ecule adopts an E geometry with respect to the C=N bond and the benzene rings are oriented at a dihedral angle of 45.3 (2)°. An intra-molecular O-H⋯N hydrogen bond helps to establish the conformation. In the crystal, the methanol solvent mol-ecule is linked to the Schiff base mol-ecule through an O-H⋯O hydrogen bond and inter-molecular N-H⋯O hydrogen bonds link the components to form layers parallel to the bc direction. ...[more]

PMID: 21577635

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