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O-Toluene-sulfonamide: a redetermination.

ABSTRACT: The structure of the title compound, C(7)H(9)NO(2)S, was previously determined from powder diffraction data [Tremayne, Seaton & Glidewell (2002). Acta Cryst. B58, 823-834]. It has now been refined to a significantly higher precision. The amino N-atom is bent with a C-C-S-N torsion angle of -65.8?(2)deg;. In the crystal, mol-ecules are packed into a three-dimensional framework/supramolecular structure through hydrogen bonds between the two H atoms of the sulfonamide group and sulfonyl O atoms of neighbouring mol-ecules.

SUBMITTER: Gowda BT

PROVIDER: S-EPMC2970068 | biostudies-literature | 2009 Aug

REPOSITORIES: biostudies-literature

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o-Toluene-sulfonamide: a redetermination.

Gowda B Thimme BT Foro Sabine S Shakuntala K K Fuess Hartmut H

Acta crystallographica. Section E, Structure reports online 20090829 Pt 9

The structure of the title compound, C(7)H(9)NO(2)S, was previously determined from powder diffraction data [Tremayne, Seaton & Glidewell (2002). Acta Cryst. B58, 823-834]. It has now been refined to a significantly higher precision. The amino N-atom is bent with a C-C-S-N torsion angle of -65.8 (2)deg;. In the crystal, mol-ecules are packed into a three-dimensional framework/supramolecular structure through hydrogen bonds between the two H atoms of the sulfonamide group and sulfonyl O atoms of ...[more]

PMID: 21577654

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