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3-(6-Benz-yloxy-2,2-dimethyl-perhydro-furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro-phen-yl)-4-nitro-2-phenyl-2,3,4,5-tetra-hydro-isoxazole.

ABSTRACT: In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by inter-molecular C-H?? inter-actions between a benz-yloxy methyl-ene H atom and the 4-chloro-phenyl ring of an adjacent mol-ecule, and by weak non-classical inter-molecular C-H?O hydrogen bonds. In addition, the crystal structure exhibits a Cl?O halogen bond of 3.111?(3)?Å, with a nearly linear C-Cl?O angle of 160.7?(1)°.

SUBMITTER: Nizammohideen M 

PROVIDER: S-EPMC2970260 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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3-(6-Benz-yloxy-2,2-dimethyl-perhydro-furo[2,3-d][1,3]dioxolan-5-yl)-5-(4-chloro-phen-yl)-4-nitro-2-phenyl-2,3,4,5-tetra-hydro-isoxazole.

Nizammohideen M M   Damodiran M M   Subbiahpandi A A   Perumal P T PT  

Acta crystallographica. Section E, Structure reports online 20090905 Pt 10

In the title compound, C(29)H(29)ClN(2)O(7), the isoxazole and dioxolane rings adopt envelope conformations, and the furan ring adopts a twisted conformation. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions between a benz-yloxy methyl-ene H atom and the 4-chloro-phenyl ring of an adjacent mol-ecule, and by weak non-classical inter-molecular C-H⋯O hydrogen bonds. In addition, the crystal structure exhibits a Cl⋯O halogen bond of 3.111 (3) Å, with a nearly linear C-Cl⋯O  ...[more]

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