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Catena-Poly[[pyridinecopper(II)]-?-N-[(2-oxido-1-naphth-yl)methyl-ene]glycinato].

ABSTRACT: In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu-O bond [2.3520?(16)?Å] is much longer than the basal Cu-O and Cu-N bonds [1.9139?(14)-2.0136?(17)?Å]. The carboxyl-ate group bridges Cu(II) atoms, forming a zigzag chain along the a axis.

SUBMITTER: Xue LW

PROVIDER: S-EPMC2970287 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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catena-Poly[[pyridinecopper(II)]-μ-N-[(2-oxido-1-naphth-yl)methyl-ene]glycinato].

Xue Ling-Wei LW Li Xing-Wu XW Zhao Gan-Qing GQ Peng Qin-Long QL

Acta crystallographica. Section E, Structure reports online 20090926 Pt 10

In the title compound, [Cu(C(13)H(9)NO(3))(C(5)H(5)N)], the Cu(II) atom is coordinated in a distorted square-pyramidal geometry, with two N and two O atoms in the basal positions and one O atom in the apical position. The apical Cu-O bond [2.3520 (16) Å] is much longer than the basal Cu-O and Cu-N bonds [1.9139 (14)-2.0136 (17) Å]. The carboxyl-ate group bridges Cu(II) atoms, forming a zigzag chain along the a axis. ...[more]

PMID: 21577755

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