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Poly[(?(3)-5-bromo-nicotinato)(5-bromo-nicotinato)copper(II)].

ABSTRACT: The title coordination polymer, [Cu(C(6)H(3)BrNO(2))(2)](n), is composed of two structurally similar two-dimensional coordination polymers (twin layers). Both of them have the same chemical composition but they display different bond lengths and angles. In each layer, two N atoms and four carboxyl-ate O atoms from the bridging 5-bromo-nicotinate ligands and four carboxyl-ate O atoms from the terminal 5-bromo-nicotinate ligands bind to two Cu(II) atoms to form a dinuclear paddle-wheel-like pattern. Adjacent paddle wheels are further linked by bridging 5-bromo-nicotinate groups to generate a two-dimensional coordination polymer; neighboring twin-like layers are finally stacked through ?-? stacking interactions between adjacent pyridine rings [perpendicular distance of 3.626?(2)?Å] in a 'sandwich' manner, thus generating a three-dimensional supra-molecular structure.

SUBMITTER: Yang J

PROVIDER: S-EPMC2970337 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Poly[(μ(3)-5-bromo-nicotinato)(5-bromo-nicotinato)copper(II)].

Yang Jun J Chen Hong-Ji HJ

Acta crystallographica. Section E, Structure reports online 20090930 Pt 10

The title coordination polymer, [Cu(C(6)H(3)BrNO(2))(2)](n), is composed of two structurally similar two-dimensional coordination polymers (twin layers). Both of them have the same chemical composition but they display different bond lengths and angles. In each layer, two N atoms and four carboxyl-ate O atoms from the bridging 5-bromo-nicotinate ligands and four carboxyl-ate O atoms from the terminal 5-bromo-nicotinate ligands bind to two Cu(II) atoms to form a dinuclear paddle-wheel-like patter ...[more]

PMID: 21577774

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