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10-Methoxy-benzo[g]imidazo[1,2-a][1,8]naphthyridine-4-carbonitrile.

ABSTRACT: In the title compound, C(16)H(10)N(4)O, both the meth-oxy and nitrile substituents lie in the plane defined by the benzo[g]imidazo[1,2-a]-1,8-naphthyridine ring system, resulting in a nearly planar geometry for the entire mol-ecule (r.m.s. deviation of the non-H atoms from the mean plane is 0.044?Å). In the solid-state, the mol-ecules form a three-dimensional polymer through inter-molecular C-H?N and C-H?O hydrogen bonds. In addition, the packing mode results in stabilizing ?-? stacking inter-actions between the asymmetric units.

SUBMITTER: Tarasov AV

PROVIDER: S-EPMC2970372 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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10-Methoxy-benzo[g]imidazo[1,2-a][1,8]naphthyridine-4-carbonitrile.

Tarasov Andrii V AV Volovnenko Tatyana A TA Lugan Noël N Volovenko Yulian M YM

Acta crystallographica. Section E, Structure reports online 20090926 Pt 10

In the title compound, C(16)H(10)N(4)O, both the meth-oxy and nitrile substituents lie in the plane defined by the benzo[g]imidazo[1,2-a]-1,8-naphthyridine ring system, resulting in a nearly planar geometry for the entire mol-ecule (r.m.s. deviation of the non-H atoms from the mean plane is 0.044 Å). In the solid-state, the mol-ecules form a three-dimensional polymer through inter-molecular C-H⋯N and C-H⋯O hydrogen bonds. In addition, the packing mode results in stabilizing π-π stacking inter-ac ...[more]

PMID: 21577970

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