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Trineodymium(III) penta-iron(III) dodeca-oxide, Nd(3)Fe(5)O(12).


ABSTRACT: The title compound, Nd(3)Fe(5)O(12) (NdIG), has an iron garnet structure. One of the Fe atoms is coordinated by six O atoms in a slightly distorted octa-hedral geometry and has site symmetry. The other Fe atom is coordinated by four O atoms in a slightly distorted tetra-hedral geometry and has site symmetry. The FeO(6) octa-hedron and FeO(4) tetra-hedron are linked together by corners. The Nd atom is coordinated by eight O atoms in a distorted dodeca-hedral geometry and has 222 site symmetry. The O atoms occupy general positions.

SUBMITTER: Komori T 

PROVIDER: S-EPMC2970433 | biostudies-literature | 2009 Sep

REPOSITORIES: biostudies-literature

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Trineodymium(III) penta-iron(III) dodeca-oxide, Nd(3)Fe(5)O(12).

Komori Takashi T   Sakakura Terutoshi T   Takenaka Yasuyuki Y   Tanaka Kiyoaki K   Okuda Takashi T  

Acta crystallographica. Section E, Structure reports online 20090926 Pt 10


The title compound, Nd(3)Fe(5)O(12) (NdIG), has an iron garnet structure. One of the Fe atoms is coordinated by six O atoms in a slightly distorted octa-hedral geometry and has site symmetry. The other Fe atom is coordinated by four O atoms in a slightly distorted tetra-hedral geometry and has site symmetry. The FeO(6) octa-hedron and FeO(4) tetra-hedron are linked together by corners. The Nd atom is coordinated by eight O atoms in a distorted dodeca-hedral geometry and has 222 site symmetry. Th  ...[more]

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