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(2-Methyl-1-phenyl-sulfonyl-1H-indol-3-yl)phenyl-methyl acetate.

ABSTRACT: In the title compound, C(24)H(21)NO(4)S, the indole ring system makes dihedral angles of 77.8 (1) and 85.4 (1)°, respectively, with the S- and C-bound phenyl rings. The mol-ecular structure is stabilized by a weak intra-molecular C-H⋯O hydrogen bond. In the crystal, a weak inter-molecular C-H⋯O hydrogen bond and a C-H⋯π inter-action are also observed.

SUBMITTER: Saravanan B

PROVIDER: S-EPMC2970969 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(3-Phenyl-sulfanyl-1-phenyl-sulfonyl-1H-indol-2-yl)methyl acetate.

Project description:In the title compound, C(23)H(19)NO(4)S(2), the indole ring system makes dihedral angles of 89.6 (1) and 84.5 (8)° with the phenyl-sulfonyl and phenyl-sulfanyl rings, respectively. In the crystal, the mol-ecules are linked into C(10) chains running along the c axis by an inter-molecular C-H⋯O hydrogen bond. In addition, the crystal packing is stabilized by C-H⋯π inter-actions.

| S-EPMC3089099 | biostudies-literature

(2-Methyl-1-phenyl-sulfonyl-1H-indol-3-yl)methanol.

Project description:In the title compound, C(16)H(15)NO(3)S, the plane of the phenyl ring forms a dihedral angle of 80.37?(8)° with the indole ring system. The crystal packing is stabilized by weak O-H?O hydrogen bonds which link the mol-ecules into infinite chains along the a axis of the crystal.

| S-EPMC2960400 | biostudies-literature

Phen-yl(3-methyl-1-phenyl-sulfonyl-1H-indol-2-yl)methanone.

Project description:In the title compound, C(22)H(17)NO(3)S, the N atom of the indole ring system deviates by 0.031?(3)?Å from a least-squares plane fitted through all nine non-H ring atoms. The geometry around the S atom can be described as distorted tetra-hedral. As a result of the electron-withdrawing character of the phenyl-sulfonyl groups, the N-Csp(2) bond lengths are longer than the typical mean value for N atoms with a planar configuration.

| S-EPMC3089169 | biostudies-literature

(E)-Methyl 3-(2-methyl-1-phenyl-sulfonyl-1H-indol-3-yl)but-2-enoate.

Project description:In the title compound, C(20)H(19)NO(4)S, the indole ring system is planar [r.m.s. deviation = 0.023?(2)?Å]. The sulfonyl-bound phenyl ring is almost perpendicular to the indole ring system [dihedral angle = 86.75?(7)°]. The ester group is almost planar (r.m.s. deviation = 0.030?Å) and is oriented at an angle of 62.53?(5)° with respect to the indole ring system. Mol-ecules are linked into a two-dimensional network parallel to the ab plane by inter-molecular C-H?O hydrogen bonds.

| S-EPMC2968289 | biostudies-literature

Phen-yl(1-phenyl-sulfonyl-1H-indol-2-yl)methanone.

Project description:The asymmetric unit of the title compound, C(21)H(15)NO(3)S, contains two crystallographically independent mol-ecules. As a result of the electron-withdrawing character of the phenyl-sulfonyl groups, the N-Csp(2) bond lengths are slightly longer than the anti-cipated value of approximately 1.35 Å for N atoms with planar configurations. Both unique S atoms have a distorted tetra-hedral configuration. In each mol-ecule, the indole ring system is essentially planar (r.m.s. deviations for all non-H atoms of 0.020 and 0.023 Å). In one mol-ecule, the indole ring system makes dihedral angles of 65.7 (8) and 73.4 (8)°, respectively, with the benzene and phenyl rings [62.2 (7) and 72.1 (7)°, respectively, in the other mol-ecule].

| S-EPMC3099964 | biostudies-literature

Diethyl 2-[(2-benzyl-1-phenyl-sulfonyl-1H-indol-3-yl)methyl-ene]malonate.

Project description:In the title compound, C(29)H(27)NO(6)S, the sulfonyl-bound phenyl ring is almost perpendicular to the indole ring system [dihedral angle = 87.96 (6)°], while the benzyl-phenyl ring is oriented at an angle of 76.8 (7)°. An intra-molecular C-H⋯O hydrogen bond is observed. In the crystal structure, mol-ecules are linked into a zigzag C(10) chain along the b axis by inter-molecular C-H⋯O hydrogen bonds.

| S-EPMC2967933 | biostudies-literature

Crystal structure of (2-bromo-methyl-1-phenyl-sulfonyl-1H-indol-3-yl)(phen-yl)methanone.

Project description:In the title compound, C22H16BrNO3S, the phenyl rings make dihedral angles of 84.81 (16) and 61.67 (17)° with the indole ring system (r.m.s. deviation = 0.012 Å), while the phenyl rings are inclined to one another by 69.5 (2)°. The mol-ecular structure is stabilized by weak intra-molecular C-H⋯O hydrogen bonds. The sulfonyl S atom has a distorted tetra-hedral configuration. In the crystal, there are no significant inter-molecular inter-actions present.

| S-EPMC4384623 | biostudies-literature

Diethyl 2-[(5-meth-oxy-2-methyl-1-phenyl-sulfonyl-1H-indol-3-yl)methyl-ene]malonate.

Project description:In the title compound, C(24)H(25)NO(7)S, the sulfonyl-bound phenyl ring is approximately perpendicular to the indole ring system [dihedral angle = 87.72?(5)°]. The methyl group of one of the ester units is disordered over two positions with occupancies of 0.527?(13) and 0.473?(13). An intra-molecular C-H?O hydrogen bond is observed. In the crystal structure, mol-ecules are linked into a ribbon structure running along the c axis by inter-molecular C-H?O hydrogen bonds and C-H?? inter-actions involving the pyrrole ring.

| S-EPMC2969626 | biostudies-literature

N-[(3-Phenyl-sulfanyl-1-phenyl-sulfonyl-1H-indol-2-yl)meth-yl]propionamide.

Project description:In the title compound, C(24)H(22)N(2)O(3)S(2), the phenyl rings form dihedral angles of 75.2?(1) and 86.1?(1)° with the indole ring system. The mol-ecular structure is stabilized by intra-molecular C-H?O and N-H?O hydrogen bonds. The crystal structure exhibit inter-molecular N-H?O and C-H?O hydrogen bonds, C-H?? and ?-? [centroid-centroid distance = 3.748?(1)?Å] inter-actions.

| S-EPMC2971435 | biostudies-literature

(1-Phenyl-sulfonyl-1H-indol-2-yl)(thio-phen-2-yl)methanone.

Project description:The crystal studied of the title compound, C(19)H(13)NO(3)S(2), was found to be a non-merohedral twin with a domain ratio of 0.877?(3):0.123?(3). There are two independent mol-ecules in the asymmetric unit. The dihedral angles between the mean plane of the indole ring system and the phenyl-sulfonyl ring are 71.67?(13) and 71.95?(13)° in the two mol-ecules while the indole unit and the thiophene ring make dihedral angles of 54.91?(12) and 56.92?(13)° in the two molecules. The crystal packing is stabilized by weak C-H?? inter-actions.

| S-EPMC3052024 | biostudies-literature

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