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(3,5-Dimethyl-pyrazol-1-yl)[5-(3,5-dimethyl-pyrazol-1-ylcarbon-yl)-2-thien-yl]methanone.

ABSTRACT: The title compound, C(16)H(16)N(4)O(2)S, crystallizes with two symmetry-independent half-mol-ecules in the asymmetric unit. All non-H atoms in each molecule lie in a crystallographic mirror plane. The mol-ecules form sheets in the ac plane, which then form stacks along the b axis. The sheets are connected via π-π stacking inter-actions [centroid-centroid distance between pyrazolato rings = 3.6949 (8) Å].

SUBMITTER: Guzei IA

PROVIDER: S-EPMC2970996 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Dichlorido(3,5-dimethyl-1H-pyrazole)[(3,5-dimethyl-1H-pyrazol-1-yl)(o-tol-yl)methanone]palladium(II).

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Project description:In the crystal of the title compound, C(8)H(13)N(3)O, mol-ecules are linked by inter-molecular N-H?N and N-H?O hydrogen bonds into a three-dimensional network. Additional stabilization is provided by weak inter-molecular C-H?O hydrogen bonds.

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