Unknown

Dataset Information

0

Catena-Poly[[zinc(II)-bis-[?-1,3-bis-(imidazol-1-ylmeth-yl)benzene-?N:N]] dinitrate methanol solvate].

ABSTRACT: In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M(2)L(2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted tetra-hedral geometry being coordinated by four N atoms from four 1,3-bis-(imidazol-1-ylmeth-yl)benzene ligands. The nitrate ions and methanol solvent mol-ecules are located between adjacent double-stranded chains and participate in an extensive net of O-H?O and C-H?O hydrogen bonds. The resulting three-dimensional assembly is further stabilized by ?-? inter-actions between benzene rings [centroid-centroid distances = 3.878?(2) and 3.853?(2)?Å].

SUBMITTER: Dobrzanska L 

PROVIDER: S-EPMC2971030 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[zinc(II)-bis-[μ-1,3-bis-(imidazol-1-ylmeth-yl)benzene-κN:N]] dinitrate methanol solvate].

Dobrzańska Liliana L  

Acta crystallographica. Section E, Structure reports online 20091010 Pt 11

In the title coordination compound, {[Zn(C(14)H(14)N(4))(2)](NO(3))(2)·CH(3)OH}(n), the cationic complex forms a looped chain containing 24-membered M(2)L(2) rings. The ligand adopts two distinct conformations that are alternated in subsequent loops. The Zn(II) ion displays a slightly distorted tetra-hedral geometry being coordinated by four N atoms from four 1,3-bis-(imidazol-1-ylmeth-yl)benzene ligands. The nitrate ions and methanol solvent mol-ecules are located between adjacent double-strand  ...[more]

Similar Datasets

Unknown catena-Poly[[[diaqua-manganese(II)]-bis-[μ-1,3-bis-(1H-imidazol-1-ylmeth-yl)benzene-κN:N]] dinitrate].
| S-EPMC3246916 | biostudies-literature
Unknown Bis[?-1,2-bis-(1H-imidazol-1-ylmeth-yl)benzene-?N:N]disilver(I) 3-carboxyl-ato-4-hydroxy-benzene-sulfonate methanol solvate trihydrate.
| S-EPMC2970038 | biostudies-other
Unknown Poly[bis[?-1,3-bis-(imidazol-1-ylmeth-yl)benzene-?N:N]bis-(nitrato-?O)cadmium].
| S-EPMC3151839 | biostudies-other
Unknown catena-Poly[[bis-(4-carboxy-cyclo-hexane-carboxyl-ato-?O,O)cadmium(II)]-?-1,4-bis-(imidazol-1-ylmeth-yl)benzene-?N:N].
| S-EPMC2969484 | biostudies-literature
Unknown catena-Poly[[[bis-(nitrato-?O)copper(II)]-bis-[?-1,3-bis-(imidazol-1-yl)-5-methyl-benzene-?(2)N(3):N(3')]] dihydrate].
| S-EPMC3379180 | biostudies-literature
Unknown Poly[[?(2)-1,2-bis-(1H-imidazol-1-ylmeth-yl)benzene-?N:N](?(2)-tereph-thalato-?O:O)zinc(II)].
| S-EPMC3009079 | biostudies-literature
Unknown catena-Poly[[dichloridozinc(II)]-?-1,4-bis-(1H-imidazol-1-yl)benzene].
| S-EPMC3011715 | biostudies-literature
Unknown Bis[?-1,4-bis-(4,5-dihydro-1H-imidazol-2-yl)benzene-?N:N]silver(I) dinitrate dihydrate.
| S-EPMC2960425 | biostudies-literature
Unknown 1,3-Bis(2-ethoxy-phen-yl)triazene methanol 0.33-solvate.
| S-EPMC2970393 | biostudies-literature
Unknown Poly[[?(2)-1,3-bis-(imidazol-1-ylmeth-yl)benzene][?(2)-2,2'-dihy-droxy-1,1'-methyl-enebis(naphthalene-3-carboxyl-ato)]zinc].
| S-EPMC3274865 | biostudies-other