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(4-Bromo-phen-yl)(1H-indol-7-yl)methanone.

ABSTRACT: In the crystal, the mol-ecules of the title compound, C(15)H(10)BrNO, are connected into centrosymmetric dimers by pairs of N-H?O hydrogen bonds. The dihedral angle between the planes of indole ring system and benzene ring is 50.13?(5)°. The indole plane is significantly less twisted from the plane of the central C-C(=O)-C bridge than the benzene plane [dihedral angles = 15.51?(3) and 40.13?(7)°, respectively]. The bond angles within the benzene ring show an approximately additive effect of the influence of both substituents.

SUBMITTER: Dutkiewicz G

PROVIDER: S-EPMC2971073 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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(4-Bromo-phen-yl)(1H-indol-7-yl)methanone.

Dutkiewicz Grzegorz G Chidan Kumar C S CS Yathirajan H S HS Kubicki Maciej M

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

In the crystal, the mol-ecules of the title compound, C(15)H(10)BrNO, are connected into centrosymmetric dimers by pairs of N-H⋯O hydrogen bonds. The dihedral angle between the planes of indole ring system and benzene ring is 50.13 (5)°. The indole plane is significantly less twisted from the plane of the central C-C(=O)-C bridge than the benzene plane [dihedral angles = 15.51 (3) and 40.13 (7)°, respectively]. The bond angles within the benzene ring show an approximately additive effect of the ...[more]

PMID: 21578509

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