Browse
Submit Data
Databases
API
Help

Dataset Information

14 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Ethyl 3-[1-(2-hydroxy-phen-yl)eth-ylidene]carbazate.

ABSTRACT: The title compound, C(11)H(14)N(2)O(3), was prepared by the reaction of ethyl carbazate and 1-(2-hydroxy-phen-yl)ethanone. In the crystal structure, mol-ecules are linked by inter-molecular N-H?O hydrogen bonds, forming centrosymmetric dimers. An intra-molecular O-H?N inter-action also occurs.

SUBMITTER: Li YF

PROVIDER: S-EPMC2971139 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Ethyl 3-[1-(2-hydroxy-phen-yl)eth-ylidene]carbazate.

Li Yu-Feng YF Liu Hai-Xing HX Jian Fang-Fang FF

Acta crystallographica. Section E, Structure reports online 20091031 Pt 11

The title compound, C(11)H(14)N(2)O(3), was prepared by the reaction of ethyl carbazate and 1-(2-hydroxy-phen-yl)ethanone. In the crystal structure, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds, forming centrosymmetric dimers. An intra-molecular O-H⋯N inter-action also occurs. ...[more]

PMID: 21578511

Similar Datasets

Ethyl 3-[1-(4-bromo-phen-yl)eth-ylidene]carbazate.

Project description:In the crystal of the title compound, C(10)H(11)BrN(2)O(2), the mol-ecules are linked by N-H?O hydrogen bonds, forming S(4) chains propagating in [100]. A C-H?O inter-action also occurs.

| S-EPMC2971419 | biostudies-literature

Ethyl 3-(3-eth-oxy-2-hydroxy-benzyl-idene)carbazate.

Project description:In the title compound, C(12)H(16)N(2)O(4), an intra-molecular O-H?O hydrogen bond occurs. In the crystal, mol-ecules are linked by N-H?O hydrogen bonds, forming chains propagating in the [010] direction.

| S-EPMC2971398 | biostudies-literature

2-{1-[2-(Bis{2-[1-(5-chloro-2-hydroxy-phen-yl)ethyl-ideneamino]eth-yl}amino)-ethyl-iminio]eth-yl}-4-chloro-phenolate toluene hemisolvate.

Project description:In the toluene hemisolvated tripodal tris-(2-amino-ethyl)amine Schiff base, C(30)H(33)Cl(3)N(4)O(3)·0.5C(7)H(8), one of the three imino N atoms is protonated, forming a hydrogen bond with the O atom at an adjacent benzene ring. The other two imino N atoms act as hydrogen-bond acceptors from phenolate OH groups. The toluene solvent mol-ecule is disordered about a centre of inversion.

| S-EPMC2968323 | biostudies-literature

N-Ethyl-N-phen-yl{[eth-yl(phen-yl)carbamothio-yl]disulfan-yl}carbothio-amide.

Project description:The asymmetric unit of the title compound, C(18)H(20)N(2)S(4), contains one half-mol-ecule, the complete molecule being generated by a twofold rotation axis. The plane through the NCS(2) group [maximum deviation = 0.01 (7) Å] is orthogonal to the phenyl ring, forming a dihedral angle of 89.4 (3)°. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions.

| S-EPMC3393985 | biostudies-literature

N-{4-[(3,4-Dimethyl-phen-yl)(eth-yl)sulfamo-yl]phen-yl}-N-ethyl-acetamide.

Project description:When viewed down the central S?N axis of the title compound, C(20)H(26)N(2)O(3)S, it is apparent that the mol-ecule adopts a gauche conformation with all O atoms lying to one side of the central benzene ring; the carbonyl O atom is directed away from the central ring and the N-bound ethyl groups lie to one side of the mol-ecule. Supra-molecular helical chains aligned along the b axis and sustained by C-H?O contacts feature in the crystal packing. These are consolidated in the three-dimensional structure by C-H?? inter-actions.

| S-EPMC3011401 | biostudies-literature

Methyl 3-[(E)-1-(4-amino-phen-yl)ethyl-idene]dithio-carbazate.

Project description:The title compound, C(10)H(13)N(3)S(2), was obtained from a condensation reaction of methyl dithio-carbazate and 4-amino-acetophenone. In the crystal structure, the nearly planar mol-ecule assumes an E configuration, the benzene ring and dithio-carbazate group being located on opposite sides of the N=C bond. C-H?? inter-actions and N-H?S hydrogen bonding are present in the crystal structure.

| S-EPMC2961396 | biostudies-literature

Ethyl N-[2-(4-phen-oxy-phen-oxy)eth-yl]carbamate.

Project description:The title compound, C(17)H(19)NO(4), which is a non-toxic insect growth regulator with the common name fenoxycarb, contains two independent and conformationally different mol-ecules in the asymmetric unit. Although the inter-ring dihedral angles are similar [62.21?(15) and 63.00?(14)°], the side-chain orientations differ. In the crystal, the mol-ecules are linked through N-H?O hydrogen-bonding associations, giving chains which extend along [110], while intra- and inter-molecular aromatic C-H?? inter-actions give sheet structures parallel to [110].

| S-EPMC3470196 | biostudies-literature

Bis[eth-yl(2-hydroxy-ethyl)aza-nium] 2,2'-disulfanediyldibenzoate.

Project description:The asymmetric unit of the title salt, 2C(4)H(12)NO(+)·C(14)H(8)O(4)S(2) (2-), contains an eth-yl(2-hydr-oxy)aminium cation and half a 2,2'-disulfanediyldibenzoate anion, with the latter disposed about a twofold axis. The cation is a straight chain with the exception of the terminal hydr-oxy group [the N-C-C-O torsion angle is 66.5?(2)°]. A twisted conformation is found for the anion [the C-S-S-C torsion angle is 91.51?(9)° and the dihedral angle between the rings is 81.01?(4)°]. A supra-molecular chain with base vector [101] and a tubular topology is formed in the crystal structure mediated by charge-assisted O-H?O(-) and N(+)-H?O(-) hydrogen bonding.

| S-EPMC2983623 | biostudies-literature

Bis[4-(2-hydroxy-ethyl-amino)phen-yl] sulfone.

Project description:The title compound, C(16)H(20)N(2)O(4)S, exhibits a V-shape structure with a dihedral angle of 77.5?(11)° formed by the two benzenel rings. The mol-ecular packing is stabilized by intra-molecular and inter-molecular hydrogen bonds as well as ?-? [3.738?(3)?Å] and C-H?? inter-actions.

| S-EPMC2915238 | biostudies-literature

(E)-Ethyl N'-[1-(2-hydroxy-phen-yl)ethyl-idene]hydrazinecarboxyl-ate.

Project description:In the mol-ecule of the title compound, C(11)H(14)N(2)O(3), the dihedral angle between the benzene ring and the hydrazinecarboxyl-ate mean plane is 3.65?(12)°. Intra-molecular C-H?N and O-H?N hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 2.38?(3)° with respect to the benzene ring, and a five-membered ring having an envelope conformation. In the crystal structure, inter-molecular N-H?O and C-H?N hydrogen bonds link the mol-ecules. There is a C-H?? contact between the benzene ring and the methyl group of the ethyl substituent.

| S-EPMC2960505 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data