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(3E,5E)-1-Benzyl-3,5-dibenzyl-idenepiperidin-4-one.

ABSTRACT: In the title compound, C(26)H(23)NO, C-H?O hydrogen bonds generate a ribbon structure along the a axis. These ribbons further assemble into a one-dimensional sheet parallel to the ac plane via C-H?? inter-actions. The piperidin-4-one ring adopts a sofa conformation with the 1-benzyl group in the equatorial position, and the 3- and 5-phenyl substituents stretched out on either side. The benzyl-idene units adopt E configurations and the 1-benzyl group is disposed towards the 3- substituent of the piperidin-4-one ring.

SUBMITTER: Karthikeyan NS

PROVIDER: S-EPMC2971257 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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(3E,5E)-1-Benzyl-3,5-dibenzyl-idenepiperidin-4-one.

Karthikeyan N S NS Sathiyanarayanan K K Aravindan P G PG Rathore R S RS

Acta crystallographica. Section E, Structure reports online 20091017 Pt 11

In the title compound, C(26)H(23)NO, C-H⋯O hydrogen bonds generate a ribbon structure along the a axis. These ribbons further assemble into a one-dimensional sheet parallel to the ac plane via C-H⋯π inter-actions. The piperidin-4-one ring adopts a sofa conformation with the 1-benzyl group in the equatorial position, and the 3- and 5-phenyl substituents stretched out on either side. The benzyl-idene units adopt E configurations and the 1-benzyl group is disposed towards the 3- substituent of the ...[more]

PMID: 21578368

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