Ontology highlight
ABSTRACT:
SUBMITTER: Fang SM
PROVIDER: S-EPMC2971285 | biostudies-literature | 2009 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20091031 Pt 11
In the title coordination polymer, [Hg(2)Cl(4)(C(6)H(12)N(2))](n), each Hg(II) center within the chain is four-coordinated by one terminal Cl atom, two bridging μ(2)-Cl atoms, and one N-atom donor from a μ(2)-1,4-diaza-bicyclo-[2.2.2]octane (μ(2)-daco) ligand in a distorted tetra-hedral geometry. The daco ligand acts as an end-to-end bridging ligand and bridges adjacent Hg(II) centers, forming a chain running along [001]. Weak C-H⋯Cl hydrogen-bonding inter-actions link the chains into a three-di ...[more]