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(?-Cyclo-penta-dien-yl)(propionitrile-?N)bis-(triphenyl-phosphine-?P)ruthenium(II) trifluoro-methane-sulfonate.

ABSTRACT: The title compound, [Ru(C(5)H(5))(C(3)H(5)N)(C(18)H(15)P)(2)]CF(3)SO(3), forms yellow crystals with a distinctly hemimorphic habit. It contains a half-sandwich complex of ruthenium with a three-legged piano-stool geometry, with Ru-P = 2.3585?(4) and 2.3312?(4)?Å, and Ru-N = 2.0422?(15)?Å?as the legs. The CF(3)SO(3) (-) anion is anchored in the crystal lattice by C-H?O and C-H?F hydrogen bonds, with C?F,O distances starting at 3.125?(2)?Å.

SUBMITTER: Mauthner K

PROVIDER: S-EPMC2971339 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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(η-Cyclo-penta-dien-yl)(propionitrile-κN)bis-(triphenyl-phosphine-κP)ruthenium(II) trifluoro-methane-sulfonate.

Mauthner Klaus K Kirchner Karl K Mereiter Kurt K

Acta crystallographica. Section E, Structure reports online 20091003 Pt 11

The title compound, [Ru(C(5)H(5))(C(3)H(5)N)(C(18)H(15)P)(2)]CF(3)SO(3), forms yellow crystals with a distinctly hemimorphic habit. It contains a half-sandwich complex of ruthenium with a three-legged piano-stool geometry, with Ru-P = 2.3585 (4) and 2.3312 (4) Å, and Ru-N = 2.0422 (15) Å as the legs. The CF(3)SO(3) (-) anion is anchored in the crystal lattice by C-H⋯O and C-H⋯F hydrogen bonds, with C⋯F,O distances starting at 3.125 (2) Å. ...[more]

PMID: 21578041

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