Ontology highlight
ABSTRACT:
SUBMITTER: Viljoen JA
PROVIDER: S-EPMC2971352 | biostudies-literature | 2009 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20091017 Pt 11
The binuclear title compound, [Hf(2)(C(5)HF(6)O(2))(6)(OH)(2)]·C(3)H(6)O, contains an Hf(IV) atom which is eight coordinated and surrounded by three chelating β-diketonato 1,1,1,5,5,5-hexa-fluoro-acetyl-acetonate (hfaa) ligands and two bridging OH groups situated on a twofold rotation axis. The HfO(8) coordination polyhedron shows a slightly distorted Archimedean square anti-prismatic coordination with average Hf-O, C-O, C-C(Me) distances of 2.19 (2), 1.26 (2) and 1.49 (2) Å, respectively, and a ...[more]